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filingDate 1962-12-21-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationDate 1965-01-06-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber GB-979778-A
titleOfInvention Process for the preparation of bicycloheptadiene dimers and/or trimers
abstract Dimers and trimers of bicycloheptadiene are obtained by contacting the monomer with a complex of a metal of Group IB or VIII in a valency state below 2 complexed with an electron-yielding organic compound. Suitable conditions are 0-200 DEG C. and 1-5 atmospheres; an inert solvent may be used, particularly bicycloheptadiene or the product. The organic ligand of the catalyst may be bicycloheptadiene or a dimer or trimer thereof, an olefin, acrylonitrile and/or a triarylphosphine; carbonyl groups may also be present. The catalyst may be formed from a soluble compound of the metal, the electron yielding complexing agent and a reducing agent such as a trialkyl or alkoxydialkyl aluminium. The product may be hydrogenated in the presence of Raney nickel and before or after hydrogenation may be used as fuels for rockets.
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Total number of triples: 33.