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filingDate 1961-02-02-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationDate 1964-11-25-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber GB-976568-A
titleOfInvention A process for the production of amphoteric ion exchange resins
abstract Amphoteric ion-exchange resins are produced by reacting polyethylene-imine under mildly alkaline conditions with a halogenoaliphatic carboxylic acid or a halogeno alkyl phosphonic acid or with a salt thereof, in amounts such that not all of the N-atoms of the polyethylene-imine are substituted, and reacting the pre-polymer obtained with a polyhalogenoaliphatic compound or with a aliphatic compound containing at least one halogen atom and at least one epoxy group. The halogeno aliphatic carboxylic acid preferably contains from 2-5 carbon atoms, those specified being chloroacetic acid and b -chloropropionic acid. Specified halogeno alkyl phosphonic acids are chloromethyl and chloroethylphosphonic acid. In the pre-polymer preferably 10-30% of the nitrogen atoms should remain unsubstituted. The mildly alkaline conditions are preferably pH 10-11 at 80-100 DEG C. Specified cross-linking compounds (i.e. halogenoaliphatic compounds) are epichlorohydrin, epibromohydrin, dichlorohydrin, dichloroethyl ether, dichloroethylene, dichloropropylene and di-bromoethylene. The examples describe the preparation of (1) an a -amino carboxylic acid resin, (2) an a -aminophosphonic acid resin. Specification 976,567 also is referred to.
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