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filingDate 1961-12-27-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_9695a1fd8508a223baf327b627c5d24f
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publicationDate 1964-11-18-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber GB-975334-A
titleOfInvention Improvements relating to cellular polystyrene materials
abstract A rigid cellular material consisting of polystyrene is made by expanding bodies of a polystyrene composition and bonding these together by means of a non-cellular bonding agent, wherein the bonding agent sets sufficiently slowly to allow preferential accumulation of the bonding agent at the points of contact of the expanded polystyrene beads. Such a bonding agent may be a non-foaming liquid polyurethane-forming composition. A secondary bonding agent such as a latex binder, a liquid mixture of plaster and water or cement and water or a liquid polyurethane rubber (each exemplified) may be used to treat the bonded polystyrene material. The weight ratio of expanded bodies to bonding agent may be 7:1 to 1:10 (respectively) but preferably 3:1 to 1:5. The polystyrene bodies which may be derived from a thermally-expandable composition containing pentanes, may be intimately mixed with bonding agent in a mixer. Specific embodiments disclose moulded articles e.g. bricks, in which non-adhering materials (specified) may be used to line the mould, another embodiment is a plywood-foam laminate. The polystyrene beads used may be twice expanded. Additives to the latex binder include potassium oleate, sulphur, zinc diethyl dithiocarbamate, zinc mercaptobenzthiazole, zinc oxide, N,N1-di-b -naphthyl-p-phenylene diamine, sodium silicofluoride, zinc oxide, casein, potassium hydroxide and whiting. If a polyurethane-forming composition is used then the beads of polystyrene may be moistened with water to obtain faster bonding. If a liquid polyurethane rubber is used as a secondary bonding agent, then trimethylol-propane may be added. The non-forming liquid polyurethane-forming composition which may be used as a bonding agent, is a mixture of one or more organic compounds having at least 2 -NCX radicals (X=O or S) e.g. tolylene diisocyanate or diphenylene methane diisocyanate, and one or more organic compound having at least 2 active hydrogens e.g. polypropylene glycol triol or polyether tetrol derived from polypropylene oxide, ethylene diamine and ethylene oxide; this mixture may be catalysed by stannous octoate.
priorityDate 1961-12-27-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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