http://rdf.ncbi.nlm.nih.gov/pubchem/patent/GB-971171-A

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classificationCPCAdditional http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C08J2375-04
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filingDate 1961-05-30-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationDate 1964-09-30-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber GB-971171-A
titleOfInvention Foamed polyurethane resins having low moisture vapor transmission
abstract Polyurethane foams are manufactured by reacting a polyoxyalkylene polyol urethane prepolymer having at least two isocyanate groups per molecule with a polyoxyalkylene polyol cross-linking agent in the presence of a catalyst, a volatile organic blowing agent and a hydrophobic polyoxyalkylene glycol or polyoxyalkylene glycerol emulsifier for the reactants, which emulsifier is added to the reaction mixture just prior to carrying out the foaming reaction in a proportion to provide a foam of the required cell size. The emulsifier may be a polyoxypropylene glycol having a molecular weight of at least 2000, a polyoxybutylene glycol having a molecular weight of at least 1000, a tris(hydroxypolyoxypropylene) ether of glycerol, a higher polyoxyalkylene glycol in which the alkylene radicals contain 4 to 7 carbon atoms or their ethers e.g. their methyl, ethyl, butyl, octyl, dodecyl, isobutyl, sec-amyl, t-butyl, phenyl, alkylphenyl and halophenyl ethers. The emulsifier may also contain a small proportion of oxyalkylene radicals derived from ethylene oxide or glycidol. In examples a prepolymer, prepared by reacting tris(2-hydroxypropyl) glycerol with tolylene di-isocyanate which was added in two portions, is reacted with a cross-linking agent which is the reaction product of propylene oxide with a mixture of sucrose and glycerol in the presence of triethylene-diamine, trichlorofluoromethane, and an emulsifier which is (1) an ethylene oxide tipped tris (polyoxypropyelne) ether of glycerol, (2) a polyoxypropylene glycol or (3) a polyoxybutylene glycol, to give a foam.
priorityDate 1960-06-02-04:00^^<http://www.w3.org/2001/XMLSchema#date>
type http://data.epo.org/linked-data/def/patent/Publication

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