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classificationCPCInventive http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C69-52
classificationIPCInventive http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C69-52
filingDate 1963-04-01-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationDate 1964-08-19-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber GB-967299-A
titleOfInvention Methyl decatriene-dioate
abstract The invention comprises methyl 2, 5, 8-decatriene-1, 10 dioate and a method of preparation by reacting methyl 7-acetoxy-2, 5-heptadienoate with acetylene, carbon monoxide and methyl alcohol, in the presence of nickel carbonyl and hydrochloric acid. A temperature of from 20 to 60 DEG C. at atmospheric pressure is preferred and methyl acetate and acrylate are formed as by-products. The product is of a 2-cis-5-trans-8-cis form and may be hydrogenated on palladium to methyl sebacate, or saponified to 2, 4, 6-decatrien-1, 10-dioic acid.
priorityDate 1962-04-05-04:00^^<http://www.w3.org/2001/XMLSchema#date>
type http://data.epo.org/linked-data/def/patent/Publication

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