http://rdf.ncbi.nlm.nih.gov/pubchem/patent/GB-950142-A
Outgoing Links
| Predicate | Object |
|---|---|
| assignee | http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_dc2f7134efa50484bb359fda73782848 |
| classificationCPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C08G59-42 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C08G59-24 |
| classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C08G59-42 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C09D5-25 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C08G59-24 |
| filingDate | 1962-02-23-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| publicationDate | 1964-02-19-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| publicationNumber | GB-950142-A |
| titleOfInvention | Curable mixtures of diepoxy compounds and dicarboxylic acid anhydrides |
| abstract | Diepoxides of the formula: <FORM:0950142/C2/1> where R represents the residue obtained by elimination of 2 hydroxyl groups, of an aliphatic, saturated trihydric alcohol containing 3 to 9 carbon atoms or aliphatic, saturated trihydric ether alcohol containing 3 to 9 carbon atoms, are made by adding 2 mols of dicyclopentadiene on to 1 mol of the trihydric alcohol or ether alcohol and epoxidising the resulting adduct. A small amount of the monoadduct of 1 mol of dicyclopentadiene with 1 mol of the triol is formed as by-product, which if not removed is converted into the corresponding monoepoxide. Specified trihydric alcohols are 1:2:4-butanetriol, 1:2:6-hexanetriol, 1:1:1-trimethylol propane, 1:1:1-trimethylol ethane, 2:4-dihydroxy-2-hydroxymethylpentane and glycerol. Specified ether alcohols are the adducts of 1 mol of ethylene or propylene oxide with 1 mol of butanetriol, hexanetriol or glycerol. Boron trifluoride is the specified catalyst for the formation of the dicyclopentadiene adduct. Specified epoxidising agents are peracetic, perbenzoic, peradipic and monoperphthalic acid, mixtures of hydrogen peroxide with formic acid or succinic or acetic anhydride and hypochlorous acid in conjunction with a strong alkali. Examples are given. U.S.A. Specification 2,543,419 is referred to.ALSO:A thermocurable mixture comprises (1) a diepoxide of the formula: <FORM:0950142/C3/1> where R represents the residue obtained by elimination of two hydroxyl groups of a saturated aliphatic trihydric alcohol containing 3 to 9 carbon atoms or aliphatic saturated trihydric ether alcohol containing 3 to 9 carbon atoms, and (2) at least one dicarboxylic anhydride. Specified diepoxides are the epoxidised adducts of dicydopentadiene with a trihydric alcohol or trihydric ether alcohol. Specified dicarboxylic acid anhydrides are phthalic, tetrahydrophthalic, hexahydrophthalic, endomethylene tetrahydrophthalic, methyl nadic, hexachloroendomethylene tetrahydrophthalic, succinic, adipic, maleic, itaconic, aconitic, allyl succinic, pentenylsuccinic, hexenylsuccinic, dodecenyl succinic, vinyl oxysuccinic, 7-allyl-bicyclo-(2:2:1)-hept-5-ene-2:3-dicarboxylic, 7-Octenyl-bicyclo-(2:2:1)-hept-5-ene 2:3 - dicarboxylic and methyl - 7 - allyl - bicyclo-(2:2:1)-hept-5-ene-2:3-dicarboxylic anhydride. The reaction mixtures may also contain monoepoxides formed as by-products during the preparation of the diepoxides, mono- or polyglycidyl ethers of mono- or poly-alcohols or phenols (including novolaks), polyglycidyl esters of polycarboxylic acids, aminopolyepoxides, cycloaliphatic mono- or poly-epoxides and fillers, e.g. asphalt, bitumen, glass fibres, mica, quartz meal, cellulose, kaolin, ground dolomite and colloidal silica. Accelerators e.g. tertiary amines, quaternary ammonium compounds, alkali metal alcoholates, hexanetriol and 2:4-dihydroxy-2-hydroxymethyl pentane may also be present. In the examples epoxidised adducts of dicyclopentadiene with:-(1) to (3) glycerol; (4) and (6) 1:1:1-trimethylol propane; (5) 1:2:4-butanetriol and (7), etherified glycerol are cured with:-(1), (2), (3a), (4a) and (5) phthalic anhydride; (3b) a mixture of methyl endomethylene tetrahydrophthalic anhydride and hexachloro endomethylene-tetrahydrophthalic anhydride; (4b) tetrahydrophthalic anhydride; (6) succinic anhydride and (7) maleic anhydride. |
| priorityDate | 1961-03-07-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| type | http://data.epo.org/linked-data/def/patent/Publication |
Incoming Links
Total number of triples: 63.