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filingDate 1962-11-09-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationDate 1964-02-12-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber GB-949293-A
titleOfInvention Process for the preparation of d-fructose
abstract D-fructose is prepared by the isomerisation of D-glucose in aqueous solution using sodium or potassium aluminate as catalyst. Preferably the glucose solution is of 5-30% by weight concentration. Instead of pure D-glucose the starting solution may consist of crude starch hydrolysates or saccharose hydrolysates (invert sugar). In the latter case the amount of D-fructose formed by the isomerisation increases the amount already present from about 50% to about 80%. The preferred temperature range for the process is 25-38 DEG C. After the isomerisation has taken place the aluminium is precipitated as hydroxide and filtered off. The D-fructose may be isolated in known manner as calcium fructosate which is treated with carbamic acid to release the D-fructose which is recrystallised from methanol.
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