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filingDate 1960-08-02-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationDate 1963-10-23-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber GB-940185-A
titleOfInvention 2,3-dimethyl-butadiene-1,3-polymers and copolymers
abstract 940,185. Polymers of 2, 3-dimethyl-butadiene- 1, 3. MONTECATINI SOC. GENERALE PER L'INDUSTRIA MINERARIA E CHIMICA. Aug. 2, 1960 [Aug. 7, 1959], No. 26701/60. Drawings to Specification. Heading C3P. Homopolymers of 2,3-dimethyl-butadiene-1,3, and copolymers thereof with other conjugated diolefins are made by polymerizing the monomer or mixture of monomers in the presence of a hydrocarbon solution of a catalyst formed by reacting an organometallic compound of the formula MR n-1 X in which M is a metal of Group II or III of the MendelÚeff Periodic Table, R is an alkyl or aryl group, X is a halogen atom, and n is the valency of the metal M, with a compound of a metal of Group VIII of the Table. The polymerization may be effected batchwise or continuously. The other conjugated diolefin may be butadiene-1,3. The Group VIII compound may be a complex with pyridine. The exemplified catalyst system is diethylaluminium chloride, cobalt chloride, and pyridine. The polymers of 2,3-dimethyl-butadiene-1,3 are characterised by their infra-red spectrum and the copolymers with butadiene by having the butadiene units arranged to an extent of about 89À9% in a cis-1, 4 configuration. Specifications 914,246 and 916,000 are referred to.
priorityDate 1956-08-07-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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Total number of triples: 20.