http://rdf.ncbi.nlm.nih.gov/pubchem/patent/GB-934581-A
Outgoing Links
| Predicate | Object |
|---|---|
| assignee | http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_c7ad58d3c0b071069a8ee0cb8c8ba2e8 |
| classificationCPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C271-06 |
| classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C271-06 |
| filingDate | 1962-03-21-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| publicationDate | 1963-08-21-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| publicationNumber | GB-934581-A |
| titleOfInvention | New carbamic acid esters |
| abstract | The invention relates to carbamates of the formula <FORM:0934581/IV(a)/1> wherein R is hydrogen or methyl, R1 is a hydrogen atom or an alkyl group, and R11 is a hydrogen or halogen atom or an alkyl, alkoxy, alkylmercapto or dialkylamino group, an alkyl group in each case containing 1-4 carbon atoms. The compounds may be prepared by standard methods, e.g. (a) by reacting an appropriately substituted phenol with methyl isocyanate or with a methyl or dimethyl carbamic acid halide, or (b) by reacting an appropriately substituted chloroformic acid phenyl ester or carbonic acid bis-phenyl ester with methyl- or dimethylamine, or (c) by transesterification between an appropriately substituted phenol and phenyl N-methyl or N,N-dimethyl carbamate. Examples are given of the preparation of 2-sec.-butenylphenyl N-methyl and N,Ndimethyl carbamate, 4- and 5-methyl-2-sec.-butenylphenyl N-methyl carbamate, 4-methoxy-2-sec.-butenylphenyl N,N-dimethyl carbamate, 5-methylmercapto- and 5-dimethyl-amino-2-sec.-butenylpheny N,N-dimethylcarbamate, 2-allyl- and 2-methallyl-phenyl N,Ndimethyl carbamate, and 4-chloro- and 4,5-dichloro-2-sec. -butenylphenyl N-methyl carbamate. The products are useful as insecticides and may be used with solid or liquid diluents or carriers. Experimental results are given of the use of 2-sec.-butenylphenyl Nmethyl carbamate in an aqueous emulsion prepared by mixing the compound with dimethyl formamide and nonylphenol polyglycol ether and diluting with water.ALSO:Insecticidal compositions contain, as active ingredient, a carbamate of the formula <FORM:0934581/VI/1> wherein R is hydrogen or methyl, R1 is a hydrogen atom or an alkyl group, and R11 is a hydrogen or halogen atom or an alkyl, alkoxy, alkylmercapto or dialkylamino group, alkyl in each case containing 1-4 carbon atoms (see Group IV (b)). Carbamates specified are 2-sec.-butenylphenyl N-methyl and N,N-dimethyl carbamate, 4- and 5-methyl-2-sec.-butenylphenyl N-methyl carbamate, 4-methoxy-2-sec.-butenylphenyl N,N-dimethyl carbamate, 5-methylmercapto- and 5-dimethylamino-2-sec.-butenylphenyl N,N-dimethylcarbamate, 2-allyl-and 2-methallyl-phenyl N,N-dimethylcarbamate, and 4-chloro- and 4,5-dichloro-2-sec.-butenylphenyl N-methyl carbamate. The carbamates may be used with solid or liquid diluents or carriers. Experimental results are given of the use of 2-sec.-butenylphenyl N-methyl carbamate in an aqueous emulsion prepared by mixing the compound with dimethyl formamide and nonylphenol polyglycol ether and diluting with water. |
| priorityDate | 1961-03-21-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| type | http://data.epo.org/linked-data/def/patent/Publication |
Incoming Links
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