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filingDate 1959-09-15-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationDate 1963-07-31-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber GB-932773-A
titleOfInvention Improvements in or relating to additives for fuels for eliminating deposits in the combustion chambers of engines
abstract Gasoline compositions contain esters of organic carboxylic acids and tertiary alcohols in amounts of 0,005% up to but not including 0,1% by volume except that when the gasoline contains olefinic and/or aromatic hydrocarbons in an amount less than 10% by volume the range may be 0,005% up to 5%. In examples gasolines contain trimethyl carbinol benzoate, dimethyl ethyl carbinol benzoate, trimethyl carbinol oleate, trimethyl carbinol metatoluate, dimethyl ethyl carbinol acetate, the acetate of 1-methyl cyclohexanol, tertiary butyl isovalerianate, methyl-ethyl-isopropyl carbinol benzoate, dimethyl-benzyl carbinol benzoate, tertiary butyl cinnamate, tertiary butyl pyromucate, tertiary butyl propionate, tetraethyl lead and methyl cycloperta-dienyl manganese tricarboryl; the proportions of saturated hydrocarbons, aromatic hydrocarbons and olefinic hydrocarbons, in the gasolines are given. A list of suitable esters is given, some containing halogen, nitro and amino groups.ALSO:The following esters, said to be novel, may be prepared by the general method of Norris and Rigby, J.A.C.S. 54,2088 (1932):-oleate of tertiary butyl alcohol, benzoate of diethyl-methyl carbinol, benzoate of dimethyl-isopropyl carbinol, benzoate of methyl-ethyl isopropyl carbinol, benzoate of nitro-trimethyl carbinol, benzoate of dimethyl-benzyl carbinol, m-toluate of tertiary butyl alcohol, m-amino benzoate of tertiary butyl alcohol, pyromucate of tertiary butyl alcohol, 3-phenyl-3-benzoyloxy ethyl butyrate and 3-methyl-3-benzoyloxy-ethyl butyrate.
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