http://rdf.ncbi.nlm.nih.gov/pubchem/patent/GB-908970-A
Outgoing Links
| Predicate | Object |
|---|---|
| assignee | http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_5b3d6aa79d32a3cccdfe41f6984e2d43 |
| classificationCPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C08G63-64 |
| classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C08G63-64 |
| filingDate | 1960-05-06-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| publicationDate | 1962-10-24-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| publicationNumber | GB-908970-A |
| titleOfInvention | Process for the production of linear copolyesters |
| abstract | Linear polyesters, suitable for the manufacture of fibres, films and moulded bodies, are made by polycondensing a carbonate of an ester of an aromatic hydroxycarboxylic acid of formula <FORM:0908970/IV(a)/1> in which R is the residue obtained by the removal of the hydroxyl groups from a glycol and R1 is an arylene radical, with a diester of a dicarboxylic acid of formula <FORM:0908970/IV(a)/2> in which R11 is an alkylene radical containing 2-10 carbon atoms or an arylene radical and R111 is the residue obtained by the removal of the hydroxyl group from a glycol containing 2-8 carbon atoms. The diesters may be polycondensed in the form of their precondensates. Polycondensation is preferably effected at 240 DEG -300 DEG C., latterly under reduced pressure, in the presence of a polyesterification catalyst and possibly a solvent, a phosphorus compound or a chain-breaker (e.g. p-toluic anhydride). Both of the above esters are preferably made by ester-interchange between their alkyl esters and a glycol in the presence of an ester-interchange catalyst. The polymers are soluble in 1-methylnaphthalene, tetrahydronaphthalene, decahydronaphthalene, diphenyl oxide, diphenyl, benzophenone and phenol/tetrachloroethane. Specified starting materials are (a) Hydroxycarboxylic acids-4-hydroxybenzoic acid, 4-hydroxy-3-methyl-benzoic acid and vanillic acid; (b) Glycols-ethylene glycol, 1:2- and 1:3-propanediol, 1:4-and 1:3-butanediol, 2-methyl-1:3-propanediol, 2-ethyl-1:3-propanediol, 1:5-pentanediol, 1:6-hexanediol, 1:8-octanediol, 1:6-cyclohexanediol, p-xylylene glycol, hydroquinone-bis-(beta-hydroxyethyl ether), di- and higher polyethylene glycols, thiodiglycol and quinitol; (c) Dicarboxylic acids-acids of formula HOOC-(CH2)n-COOH, where n=2-10, isophthalic, terephthalic, and naphthalenedicarboxylic acids and acids of formula HOOC-C6H4-R-C6H4-COOH, where R is a direct link, -O-, -(CH2)n-[n=1-5], -O-(CH2)n-O- or -SO2-. In examples polyesters are obtained by condensing (1) The bis-beta-hydroxyethyl ester of 4:41-carboxy-bis-phenyl carbonate and bis-(beta-hydroxyethyl) isophthalate; (2) The dimethyl ester of 4:41-carboxy-bis-phenyl carbonate, dimethyl terephthalate and ethylene glycol; (3) A partial polymer obtained from the dimethyl ester of 4:41-carboxy-2:21-dimethyl-bis-phenyl carbonate and a partial polymer obtained from the diethyl ester of 4:41-diphenyl-dicarboxylic acid and 1:3-propanediol; (4) The dimethyl ester of 4:41-carboxy-2:21-dimethoxy-diphenyl carbonate, dimethyl terephthalate and ethylene glycol; (5) The dimethyl ester of 4:41-carboxy-bis-phenyl carbonate, the diethyl ester of p,p1-sulphonyldibenzoic acid and 1:3-propanediol; (6) The dimethyl ester of 4:41-carboxy-bisphenyl carbonate, dimethyl succinate, dimethyl terephthalate and ethylene glycol. |
| priorityDate | 1959-05-09-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| type | http://data.epo.org/linked-data/def/patent/Publication |
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