http://rdf.ncbi.nlm.nih.gov/pubchem/patent/GB-891646-A
Outgoing Links
Predicate | Object |
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assignee | http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_47becd0bad1e8c65826be1edac09d306 http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_86c830a3398b926c1e2a740bb3bbb10a |
classificationCPCAdditional | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C08F2410-04 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C08F2410-01 |
classificationCPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C08F10-00 |
classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C08F10-00 |
filingDate | 1960-11-01-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationDate | 1962-03-14-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationNumber | GB-891646-A |
titleOfInvention | Improvements relating to the polymerisation of olefins |
abstract | In a process for the polymerization of olefins there is employed a catalyst comprising (A) an organometallic compound of a metal of Group I, II or III of the Mendeleef Periodic Table and (B) two metal salts of which at least one (a) is of a metal of Group IVa, Va or VIa and at least one (b) is a salt of a metal of Group I, II, IV or VIII complexed with a nitrogenous organic base the molar ratio of (b) to (a) being at least 0,05. The olefin may be ethylene, propylene or butene. The salt (b) may be a lithium, beryllium, magnesium, cupric, cadmium, zinc, ferric, nickelous or titanium IV halide, e.g. chloride, and the preferred base is pyridine. Examples describe the use of catalysts comprising aluminium triethyl and titanium trichloride with (1) CuCl2.2Py, BeCl2.2Py, ZnCl2.-2Py, CdCl2.2Py, MgCl2.4Py, NiCl2.4Py and FeCl3.4Py; (2) NiCl2.4Py; (3, 6 and 10) ZnCl2.-2Py; (4) CdCl2.2Py; (7) LiCl2.2Py; (8) TiCl4.2Py and (9) TiCl3.3Py; and aluminium triethyl and vanadium chloride with (5) ZnCl2.2Py. Polymerization may be effected in liquid media, e.g. heptane and butane, and the products washed with methanolic hydrochloric acid and methanol. |
isCitedBy | http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-5210161-A |
priorityDate | 1959-12-18-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
type | http://data.epo.org/linked-data/def/patent/Publication |
Incoming Links
Total number of triples: 48.