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filingDate 1955-08-03-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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publicationDate 1958-07-23-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber GB-798644-A
titleOfInvention Improvements in or relating to the purification of carbon or graphite articles
abstract Carbon or graphite is purified by treatment at elevated temperature with a gaseous fluorinating agent, e.g. fluorine, hydrogen fluoride, or a fluorinated hydrocarbon which dissociates to produce fluorine or hydrogen fluoride at the temperature of treatment. Organic fluorides specified are tetrafluoro-, dichloro-, monofluoro-, dichlorodifluoro-, monochlorodifluoro-, and trichloromonofluoro-methane and mono-, di, tri- and tetrafluoro ethylene. The temperature of treatment may be 1860-2600 DEG C., preferably 2200-2600 DEG C. The material may be pretreated with a gaseous or vaporous chlorinating agent at a progressively increasing temperature initially less than 1860 DEG C., preferably increasing to a temperature in the range 1860-1950 DEG C. Chlorinating agents specified are chlorine, carbon tetrachloride, and hexachloropropylene. Nitrogen, ammonia, or helium may be used as carrier or diluent for the chlorinating and/or fluorinating agent and to sweep out the chlorinating and fluorinating agents after treatment. Petroleum coke powder bonded with coal tar pitch, and graphite prepared therefrom, may be treated. A fluorinating apparatus (Fig. 1, not shown), comprises an electric furnace comprising graphite electrodes separated by a bed of pure petroleum coke in which are placed the graphite articles to be treated. Porous tubes for introduction of the fluorinating agent are mounted below the articles.
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