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classificationCPCInventive http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07D249-08
classificationIPCInventive http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07D249-14
filingDate 1955-03-25-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationDate 1957-01-09-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber GB-765728-A
titleOfInvention Process for the production of 3- or 5-amino-1, 2, 4-triazoles
abstract 3- or 5-Amino-1 : 2 : 4-triazole and 5- or 3-(C1-C3)-alkyl derivatives thereof are produced by heating in an organic solvent capable of entraining water an acyl-aminoguanidine or salt thereof, or a mixture of an aminoguanidine salt with a fatty acid containing not more than 4 carbon atoms, the water formed during the reaction being continuously removed together with the entraining agent by distillation. Specified entraining agents are toluene, xylene and iso-octane. Specified fatty acids are formic, acetic and butyric acids. The reaction is preferably conducted at 100-150 DEG C. and in presence of basically reacting substances such as amines (e.g. dimethylaniline). Amino- and acylamino-guanidine hydrochlorides and sulphates yield the corresponding aminothiazole hydrochlorides and sulphates, from which the free bases are obtained by further treatment; aminoguanidine bicarbonate, acylaminoguanidines and bicarbonates thereof yield the free bases directly. The examples describe the preparation of 3-amino-, 3-amino-5-methyl- and 3 - amino - 5 - n - propyl - 1 : 2 : 4 - triazoles. Specification 520,394, [Group IV], is referred to.
isCitedBy http://rdf.ncbi.nlm.nih.gov/pubchem/patent/FR-2816616-A1
priorityDate 1954-03-26-04:00^^<http://www.w3.org/2001/XMLSchema#date>
type http://data.epo.org/linked-data/def/patent/Publication

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