http://rdf.ncbi.nlm.nih.gov/pubchem/patent/GB-765728-A
Outgoing Links
Predicate | Object |
---|---|
assignee | http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_c7ad58d3c0b071069a8ee0cb8c8ba2e8 |
classificationCPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07D249-08 |
classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07D249-14 |
filingDate | 1955-03-25-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationDate | 1957-01-09-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationNumber | GB-765728-A |
titleOfInvention | Process for the production of 3- or 5-amino-1, 2, 4-triazoles |
abstract | 3- or 5-Amino-1 : 2 : 4-triazole and 5- or 3-(C1-C3)-alkyl derivatives thereof are produced by heating in an organic solvent capable of entraining water an acyl-aminoguanidine or salt thereof, or a mixture of an aminoguanidine salt with a fatty acid containing not more than 4 carbon atoms, the water formed during the reaction being continuously removed together with the entraining agent by distillation. Specified entraining agents are toluene, xylene and iso-octane. Specified fatty acids are formic, acetic and butyric acids. The reaction is preferably conducted at 100-150 DEG C. and in presence of basically reacting substances such as amines (e.g. dimethylaniline). Amino- and acylamino-guanidine hydrochlorides and sulphates yield the corresponding aminothiazole hydrochlorides and sulphates, from which the free bases are obtained by further treatment; aminoguanidine bicarbonate, acylaminoguanidines and bicarbonates thereof yield the free bases directly. The examples describe the preparation of 3-amino-, 3-amino-5-methyl- and 3 - amino - 5 - n - propyl - 1 : 2 : 4 - triazoles. Specification 520,394, [Group IV], is referred to. |
isCitedBy | http://rdf.ncbi.nlm.nih.gov/pubchem/patent/FR-2816616-A1 |
priorityDate | 1954-03-26-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
type | http://data.epo.org/linked-data/def/patent/Publication |
Incoming Links
Total number of triples: 38.