http://rdf.ncbi.nlm.nih.gov/pubchem/patent/GB-758165-A
Outgoing Links
| Predicate | Object |
|---|---|
| assignee | http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_9799ffcda2dbb45041a5ab0fd08dd5fe |
| classificationCPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07K1-006 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/G03C7-3212 |
| classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/G03C7-32 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07K1-00 |
| filingDate | 1954-08-30-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| publicationDate | 1956-10-03-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| publicationNumber | GB-758165-A |
| titleOfInvention | Compounds containing an isophthalate group useful in photography |
| abstract | The invention comprises compounds useful as colour couplers having the general formula: <FORM:0758165/IV(a)/1> wherein R is H or alkyl, Y is H, CH3. or alkali metal, and Z is an aromatic radical connected to a group containing a coupling function. As values of Z are mentioned: (1) an aryl radical connected to the 3-position of a 1-alkyl-5-pyrazolone or a 1-aryl-5-pyrazolone; (2) a benzene ring containing a 2,4-di-tert-amylphenoxy substituent; (3) a benzene ring connected to the carbon atom of a -CO.NH-group, the nitrogen of which is connected to the group containing a coupling function; (4) a benzene ring connected to a -COCH2.CONH-aryl group. They are made by condensing a compound of the formula: <FORM:0758165/IV(a)/2> with an amine Z-NH2, preferably in presence of an acid binding agent and an organic diluent. The compounds may be incorporated in photographic silver halide emulsions or photographic developers containing primary aromatic amino developing agents, e.g. an alkylated phenylene diamine. In examples, 3,5-dicarbomethoxyphenoxy acetyl chloride is reacted in anhydrous acetic acid or in acetonitrile with amines of the following formul : <FORM:0758165/IV(a)/3> (prepared by condensing ethylene diamine with phenyl - 1 - hydroxy - 2 - naphthoate, and condensing the amide with 2(2:4-di-tert.-amylphenoxy) - 5 - nitrobenzoyl chloride, and reduction of the nitro group; <FORM:0758165/IV(a)/4> (prepared according to Specification 737,103). <FORM:0758165/IV(a)/5> (prepared by condensing 4-amino-2.6-dichloro-m-cresol with 4-(21.41-di-tert.-amylphenoxy)-3-nitrobenzoyl chloride and reduction of the nitro group). <FORM:0758165/IV(a)/6> (prepared by condensation of sodium 2.4-di-tert.-amyl phenate with o-chloronitrobenzene, reduction, condensation with ethyl p-nitrobenzoylacetate and again reduction). Also in examples 3.5-dicarbomethoxyphenoxy butyryl chloride is reacted with amines of the formul <FORM:0758165/IV(a)/7> (prepared by condensing 4-amino-2.6-dichloro-m-cresol with 2-(21.41-di-tert.-amylphenoxy)-5-nitrobenzoyl chloride and reduction). <FORM:0758165/IV(a)/8> <FORM:0758165/IV(a)/9> Other products are listed as prepared similarly. 3.5-Dichloroformyl phenol is prepared from 3.5-dicarboxyphenol and thionyl chloride. 3.5-Dicarbomethoxyphenol was prepared from 3.5-dichloroformyl phenol and methanol. 3.5-Dicarbomethoxyphenoxyacetic acid and 3.5-dicarbomethoxyphenoxybutyric acid are prepared from 3.5-dicarbomethoxyphenol and bromacetic acid or bromobutyric acid in methanol in presence of sodium methoxide. Specifications 562,205, [Group IV], and 737,112 also are referred to. |
| priorityDate | 1953-09-02-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| type | http://data.epo.org/linked-data/def/patent/Publication |
Incoming Links
Total number of triples: 49.