http://rdf.ncbi.nlm.nih.gov/pubchem/patent/GB-757773-A

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classificationCPCAdditional http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/Y10T436-212
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http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C08F22-30
filingDate 1954-09-13-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_f749088c3ef7339e8c12f6a19d5a6f88
http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_7ee6bf905fa90adfa86327080e5dd45a
publicationDate 1956-09-26-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber GB-757773-A
titleOfInvention Improvements in polymerizable nitrile and polymeric product obtained therefrom
abstract Polymers of tetracyanoethylene are made by polymerizing it alone or in admixture with other monomers, preferably in presence of a polymerization catalyst. The polymerization may be effected in bulk, in organic solvent solution, e.g. benzene, or by the addition of aqueous ammonium or sodium hydroxide solutions. Other monomers mentioned are acrylonitrile, ethylene, isobutylene, propylene and styrene. Specified catalysts are a :a 1-azobis-(a :g -dimethylvaleronitrile) and di-(tertiarybutyl) peroxide. The polymers may be used for electrical insulation purposes.ALSO:The invention comprises tetracyanoethylene and the preparation thereof by reacting malononitrile with sulphur monochloride under anhydrous conditions and preferably in an inert liquid diluent. The molar ratio of sulphur monochloride to malononitrile is preferably within the range of 1:2 to 2:1, and the reaction is preferably conducted at temperatures of 50-125 DEG C. The crude tetracyanoethylene may be purified by sublimation to give a white crystalline product.
isCitedBy http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-3267115-A
http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-3026348-A
priorityDate 1954-09-13-04:00^^<http://www.w3.org/2001/XMLSchema#date>
type http://data.epo.org/linked-data/def/patent/Publication

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