http://rdf.ncbi.nlm.nih.gov/pubchem/patent/GB-730328-A
Outgoing Links
| Predicate | Object |
|---|---|
| assignee | http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_fb78b459e21bb4fd52850a12cab27387 |
| classificationCPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C69-54 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C69-63 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C69-653 |
| classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C69-653 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C69-63 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C69-54 |
| filingDate | 1953-03-10-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| publicationDate | 1955-05-18-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| publicationNumber | GB-730328-A |
| titleOfInvention | Improvements in or relating to a process for preparing ª:ª-dichlorpropionates |
| abstract | a : b -Dichloropropionic esters of monohydric alcohols are prepared by reacting chlorine with acrylic acid esters of monohydric alcohols in the presence of a minor proportion of an N-substituted aliphatic carboxylic amide. The amount of amide present must be at least 1/2 per cent by weight of the acrylic ester but need not exceed 10 per cent. Preferred amides have the general formula <FORM:0730328/IV (b)/1> where R is hydrogen or an aliphatic hydrocarbon group of not more than 8 carbon atoms and R1 and R11 are hydrogen or hydrocarbon groups having not more than 12 carbon atoms, at least one of the terms R1 and R11 representing such a group, or R1 and R11 may together form a saturated divalent chain forming a heterocycle with the nitrogen atom. Numerous of such amides are mentioned including N-methyl formamide, morpholine formamide, aceto-piperidide, N-butyl acetamide, N-methyl acrylamide, N : N-diethylhexamide, N - methyl - N - phenyl acetamide, N : N-dimethadipamide and N : N : N1 : N1-tetramethylsuccinamide. The chlorination is generally effected at about 20-50 DEG C.; inert solvents such as chlorinated solvents or alcohols, e.g. glycerol and ethylene glycol may be present. The acrylate esters for the chlorination include alkyl, alkenyl, aralkyl, cycloalkyl and terpenyl acrylates and those containing inert substituents in the alcohol residue such as methoxyethyl, ethoxyethyl, dimethylaminoethyl, tetrahydrofurfuryl and ethylthioethyl groups and numerous compounds are mentioned. Examples describe the chlorination to the corresponding a : b - dichloropropionates of methyl-, ethyl-, tert. - butyl-, cyclohexyl-, benzyl-, n-octyl-, dodecyl- and octadecylacrylates. In examples 1 and 12, the resulting methyl- and tert.-butyl-a : b -dichloropropionates are treated with aqueous alkali to form the esters of a -chloroacrylic acid. Comparative tests are given showing the lower yields obtained when methanol or formamide replaces the N-substituted amide in the reaction. |
| isCitedBy | http://rdf.ncbi.nlm.nih.gov/pubchem/patent/EP-0383128-A1 http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-5072030-A |
| priorityDate | 1952-03-15-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| type | http://data.epo.org/linked-data/def/patent/Publication |
Incoming Links
Total number of triples: 46.