http://rdf.ncbi.nlm.nih.gov/pubchem/patent/GB-715434-A
Outgoing Links
Predicate | Object |
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assignee | http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_af7c9c966acd2ef7eca105d82d8d0991 |
classificationCPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C08F36-04 |
classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C08F2-22 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C08F36-04 |
filingDate | 1952-08-01-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationDate | 1954-09-15-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationNumber | GB-715434-A |
titleOfInvention | Improvements in or relating to a process for producing high polymer latices |
abstract | Monomeric material containing a CH2 = C < group is polymerized in aqueous emulsion in a polyamine organic peroxide anti-freeze system at -15 to -40 DEG C., in the presence of (1) not more than 0.8 millimols. per 100 parts monomers of a water-soluble salt of iron, cobalt, manganese, vanadium or copper and (2) 2, 21-dipyridyl ethylenediamine tetraacetic acid or an alkali metal or ammonium salt of ethylene diamine tetraacetic acid, the ratio in mols. of the metal salt to the tetraacetic compound being 1:1 to 1:5. Specified monomers are butadiene, 2, 3-dimethyl-1:3-butadiene, isoprene, piperylene, 3-furyl-1:3-butadiene, 3-methoxy-1:3-butadiene, chloroprene, bromoprene, methylchloroprene, styrene, alkyl styrenes, 1-chlorostyrene, vinyl naphthalene, acrylic acid, methacrylic acid, methylacrylate, methyl a -chloro-acrylate, methyl methacrylate, acrylonitrile, methacrylonitrile, methacrylamide, p-methoxystyrene, alpha-methylstyrene, methyl isopropenyl ketone, methyl vinyl ketone, methyl vinylether, vinylethinyl alkyl carbinols, vinyl acetate, vinyl chloride, vinylidene chloride, vinylfurane, vinylcarbazole, vinylacetylene, and others. It is preferred to use butadiene-1:3 with styrene, alpha-methylstyrene, vinyltoluene or chlorstyrene. Specified salts are iron sulphate and iron nitrate. It is preferred that the polyamine is a polyalkylene polyamine such as tetraethylene pentamine and that the peroxide is cumene peroxide. |
isCitedBy | http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-3322746-A |
priorityDate | 1951-08-06-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
type | http://data.epo.org/linked-data/def/patent/Publication |
Incoming Links
Total number of triples: 88.