http://rdf.ncbi.nlm.nih.gov/pubchem/patent/GB-680399-A
Outgoing Links
| Predicate | Object |
|---|---|
| assignee | http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_14f86e164bb6ab1032c519b42ff81a64 |
| classificationCPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C09B23-164 |
| classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C09B23-16 |
| filingDate | 1950-12-18-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| publicationDate | 1952-10-01-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| publicationNumber | GB-680399-A |
| titleOfInvention | Azathiazolone cyanine dyes |
| abstract | Dye intermediates of the general formula <FORM:0680399/IV (b)/1> wherein R is an alkyl, hydroxyalkyl, alkoxyalkyl, carboxyalkyl, carbalkoxyalkyl, acyloxyalkyl, aryl, or aralkyl group, R1 is an alkyl, allyl, aryl, or aralkyl group, n is 1 or 2, and Z represents the residue of a 5- or 6-membered heterocyclic nitrogeneous ring system, are prepared by condensing a compound of the general formula <FORM:0680399/IV (b)/2> wherein X is an acid radicle, with an isocyanate R1NCS. Amino compounds specified include 2 - aminobenzthiazole dimethylsulphate, 2 - aminobenzoxazole methiodide, 2 - amino - 5 - methylbenzoxazole metho - p - toluenesulphonate, 2 - aminobenzselenazole methiodide, 2 - amino-4-phenylozaxole methiodide, 2-amino-5-methylthiadiazole methiodide, 2 - amino - 5 - methyloxadiazole ethiodide, 2 - aminopyridine ethiodide, 2- and 4-aminoquinoline ethiodide, 2 - amino - a - naphthathiazole methiodide, 2 - amino-b -naphthathiazole ethiodide, 2-amino-5-ethoxybenzthiazole ethiodide, and 2-aminothiazole methiodide. Thiocyanates specified are methyl, ethyl, allyl, phenyl, a - and b -naphthyl, o-, m-, and p-tolyl, benzyl, and phenylethyl thiocyanates. N-(3-Ethyl-2-benzthiazolylidene) - N1 - phenylthiourea is prepared by heating together 2-aminobenzthiazole ethiodide and phenyl isothiocyanate in pyridine. N - (3 - Ethyl - 6 - ethoxy - 2 - benzthiazolylidene) - N1 - phenylthiourea, N - 3 - ethyl - 6 - ethoxy - 2 - benzthiazolylidene) - N1 - allylthiourea, N - (3 - ethyl - 5 - methyl - 4 - phenyl - 2 - thiazolylidene) - N1 - phenylthiourea, and N - (3 - methyl - 2 - benzthiazolylidene) - N1 - phenylthiourea are similarly prepared. N-(3 : 4-Dimethyl-2-thiazolylidene) - N1 - phenylthiourea is prepared by heating together 2-amino-4-methylthiazole dimethylsulphate and phenyl isothiocyanate.ALSO:Thiazolone azacyanine dyes of the general formula <FORM:0680399/IV (c)/1> wherein R is an alkyl, hydroxyalkyl, alkoxyalkyl, carboxyalkyl, carbalkoxyalkyl, acyloxyalkyl, aryl, or aralkyl group, R1 is an alkyl, allyl, aryl, or aralkyl group, X is an acid radicle, n is 1 or 2, and Z represents the residue of a 5- or 6-membered heterocyclic nitrogeneous ring system, are prepared by heating a compound of the general formula <FORM:0680399/IV (c)/2> with an a -halogen acetic acid. Dyes are prepared by heating together in glacial acetic acid bromacetic acid and N-(3-methyl-2-benzthiazolylidene) - N1 - phenylthiourea, N - (3-ethyl - 2 - benzthiazolylidene) - N1 - phenylthiourea, N - (3 - ethyl - 6 - ethoxy - 2 - benzthiazolylidene)-N1-allylthiourea, N-(3-ethyl-6-ethoxy - 2 - benzthiazolylidene) - N1 - phenylthiourea, and N-(3 : 4-dimethyl-2-thiazolylidene)-N1-phenylthiourea, by heating together in n-butanol bromacetic acid and N-(3-ethyl-5-methyl - 4 - phenyl - 2 - thiazolylidene) - N1-phenylthiourea, and by heating together in glacial acetic acid chloracetic acid and N-(3-ethyl - 2 - benzthiazolylidene) - N1 - phenylthiourea. Iodoacetic acid may also be used. The dyes may be converted to the iodides, perchlorates, or thiocyanates. |
| priorityDate | 1949-12-16-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| type | http://data.epo.org/linked-data/def/patent/Publication |
Incoming Links
Total number of triples: 63.