http://rdf.ncbi.nlm.nih.gov/pubchem/patent/GB-661185-A
Outgoing Links
Predicate | Object |
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assignee | http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_3a5173a7d063a9f70ca7b5e86fc23863 |
classificationCPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C69-734 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C69-78 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C69-92 |
filingDate | 1948-11-22-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationDate | 1951-11-21-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationNumber | GB-661185-A |
titleOfInvention | Improvements in or relating to the production of alkoxyalkyl esters of iodobenzoic acids |
abstract | Alkoxyalkyl iodobenzoates of the formula <FORM:0661185/IV (b)/1> where Y is alkylene, R is alkyl and the total number of carbon atoms in the molecule is 10-18, or of the formula <FORM:0661185/IV (b)/2> where Y is alkylene, R and R1 are alkyl and the total number of carbon atoms in the molecule is 11-16, are prepared from (1) the iodobenzoic acid or iodoalkoxybenzoic acid and an alkoxyalkanol in the presence of an acid catalyst; (2) as in (1) using a reactive derivative of the acid, e.g. chloride or anhydride, in which case no catalyst is necessary; (3) a metallic (e.g. alkali metal) salt of the iodobenzoic or iodo-alkoxy-benzoic acid and an alkoxyalkyl halide. Preferably Y has 2-3 carbon atoms, R has 1-6 and R1 has 1-2. In the examples, the following compounds are prepared: 2-ethoxyethyl o-iodobenzoate; 2-methoxyethyl and 2-ethoxyethyl m-iodobenzoates; 2-methoxyethyl, 2-ethoxyethyl, 3-methoxypropyl, 3-ethoxypropyl, 2-butoxyethyl and 2 - (21 - ethyl - butoxy) - ethyl p - iodobenzoates; 2-ethoxyethyl, 2-butoxyethyl and 5-methoxypropyl 3-iodo-4-methoxy-benzoates, 2-methoxyethyl, 2-ethoxyethyl and 3-ethoxypropyl 3 - iodo - 4 - ethoxy - benzoates; 2-ethoxyethyl 2 - iodo - 5 - methoxy - benzoate. Mixtures of two of these esters form eutectic mixtures with low melting points. |
isCitedBy | http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-7745424-B2 |
priorityDate | 1947-11-24-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
type | http://data.epo.org/linked-data/def/patent/Publication |
Incoming Links
Total number of triples: 26.