http://rdf.ncbi.nlm.nih.gov/pubchem/patent/GB-636348-A
Outgoing Links
| Predicate | Object |
|---|---|
| assignee | http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_341185d288145f6ebf30685b34deb941 http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_66e254f3de61d101d7edc9ed3bbd8502 |
| classificationCPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C08G69-26 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C08G69-28 |
| classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C08G69-28 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C08G69-26 |
| filingDate | 1947-06-18-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| publicationDate | 1950-04-26-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| publicationNumber | GB-636348-A |
| titleOfInvention | Production of synthetic polymers |
| abstract | Linear polyamides are produced by reacting a di-ester of oxalic acid with a substantially equimolecular proportion of a diprimary diamine without the application of heat. The reaction may be carried out by mixing solutions of the reagents, e.g. in alcohols, ethers, or hydrocarbons with or without catalysts such as phosphoric or benzoic acid at room temperature, whereupon the polymer precipitates. Specified are di-esters: methyl, ethyl, phenyl, and cresyl oxalates; amines: one or more of tetra-, hexa-, or decamethylene diamines, others of formula NH2(CH2)nNH2, where n is at least 3, 2,21-diaminodiethyl-ether and thioether, bis-(g -aminopropyl) - ethylamine, p - xylylene diamine, 2,5-diamino hexane. 2,21-diamino-diethyl sulphone, and 4-hydroxy-heptamethylene diamine. The solvent is selected to control the maximum temperature of the reaction or external cooling to 50 DEG C. or 25 DEG C. may be employed. The reaction may also be performed in the presence of non-solvents or in the absence of solvents. In examples: (1) equimolecular proportions of ethanol solutions of ethyl oxalate and decamethylene diamine are mixed at room temperature and the precipitated polymer is dried under vacuum. It is partially soluble in m-cresol, formic acid, formamide, and aqueous solutions of lithium bromide and zinc chloride; (2) the process of (1) is followed but with hexamethylene diamine and ethyl oxalate. Filaments may be produced by melt spinning the products and sulphonamide, phenolic, urea, or thiourea plasticizers may be added to the melt. Filaments may also be spun from solutions in formic or acetic acid, cyanohydrins, or phenolic solvents, e.g. phenol or cresol. The polymers may be mixed with cellulose acetate, acetobutyrate, butyrate, and acetostearate, ethyl cellulose, oxyethyl cellulose, oxyethyl cellulose acetate, benzyl cellulose and other cellulose derivatives, plasticizers or softening agents, dyestuffs, and pigments. |
| priorityDate | 1947-06-18-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| type | http://data.epo.org/linked-data/def/patent/Publication |
Incoming Links
Total number of triples: 63.