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filingDate 1944-07-21-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationDate 1947-01-03-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber GB-583961-A
titleOfInvention Purification of lanthanum compounds and the manufacture of glass therefrom
abstract Solutions of lanthanum salts, e.g., acetate, bromide, bromate, chloride, or nitrate are freed from iron and cerium, by adding ammonium carbonate and hydrogen peroxide or ammonium persulphate, heating above 80 DEG C. and removing the precipitate. The reagents are preferably added in only slight excess of the quantities necessary to neutralize and oxidize the solution, and may be added together or separately to a hot or cold solution. The most efficient separation is achieved by adding persulphate to the hot previously neutralized solution. Preferably salts having less than 1 per cent. impurity are treated in 25 per cent. solution, and the precipitation is performed at the boiling point. Examples describe the purification of double ammonium lanthanum nitrate. Lanthanum oxide, recovered by evaporating the filtrate and igniting, or by precipitating and igniting lanthanum oxalate, may be used with tungsten, barium, thorium and boron oxides &c. to form colourless glasses as described in Specification 534,680, (see Group XXIII).
isCitedBy http://rdf.ncbi.nlm.nih.gov/pubchem/patent/FR-2583034-A1
priorityDate 1944-07-21-04:00^^<http://www.w3.org/2001/XMLSchema#date>
type http://data.epo.org/linked-data/def/patent/Publication

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