http://rdf.ncbi.nlm.nih.gov/pubchem/patent/GB-497368-A
Outgoing Links
Predicate | Object |
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assignee | http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_73ee0bacab5a7576a6a3244747f6ea99 http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_0cb400b9ecfa16cd708555abce2b1485 http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_467810668d2cef56953a4e82a64e9ace |
classificationCPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C275-46 |
classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C275-46 |
filingDate | 1937-06-18-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationDate | 1938-12-19-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationNumber | GB-497368-A |
titleOfInvention | New nitrogen-containing organic compounds |
abstract | Urea derivatives containing an amino or quaternary ammonium group are obtained by the action of an aliphatic, cycloaliphatic or araliphatic amine, or of a heterocyclic amine containing only one heterocyclic ring, on an ester derived from a hydroxyalkyl or hydroxyacyl urea and a hydrogen halide or aromatic sulphonic acid. Examples are given of the manufacture of products from (1) 2-chlorethylurea hydrochloride and pyridine; (2) chloracetylurea and piperidine; (3) iodoacetylurea and N-benzylpiperidine; (4) pyridine and the reaction product of b -hydroxyethylurea and p-toluenesulphochloride; the picrate derived from the product is identical with the picrate derived from the product of example 1; (5) chloracetylurea and pyridine; (6) chloracetylurea and diethylamine; (7) g -chloropropylurea and pyridine; (8) 2-chlorethylurea hydrochloride and triethylamine; and (9) chloracetylurea and piperidylacetylurea, made as described in example 2. An additional urea derivative which may be treated is a -chloropropionylurea, and additional amines which may be used are methylamine, ethylamine, dimethylamine, benzylamine, cyclohexylamine, N-methylpiperidine, a -picoline, quinoline and the tertiary amines obtainable by reaction of a halogenalkyl- or halogenacyl-urea with a secondary amine. 2-Chlorethylurea hydrochloride is obtained from 2-hydroxyethylurea and thionyl chloride. g -Chloropropylurea is obtained by warming g -aminopropanol with nitrourea, and treating the g -hydroxypropylurea so obtained with thionyl chloride. |
isCitedBy | http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-4424284-A |
priorityDate | 1937-06-18-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
type | http://data.epo.org/linked-data/def/patent/Publication |
Incoming Links
Total number of triples: 57.