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filingDate 1935-01-21-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationDate 1936-07-21-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber GB-450843-A
titleOfInvention Improvements in or relating to the manufacture of alkyl halides
abstract Alkyl halides are made in a continuous process by reacting a hydrogen halide with an alcohol containing less than four carbon atoms in presence of a catalyst comprising a bismuth halide at a temperature above the boiling-point of the alcohol. The catalyst may be bismuth chloride or bromide or, initially, bisanth oxychloride and may be used fused, or in solution containing, for example, 70--90 per cent of bismuth halide, or upon a carrier such as active alumina, alundum or asbestos. Examples describe the production of methyl, ethyl and isopropyl chlorides. In one case, a mixture of ethyl alcohol and sulphuric acid is added to a mixture of sodium bisulphate, sulphuric acid, water, and rock salt and the vapours evolved are treated with the bismuth chloride catalyst. Specification 357,528 is referred to.
priorityDate 1935-01-21-04:00^^<http://www.w3.org/2001/XMLSchema#date>
type http://data.epo.org/linked-data/def/patent/Publication

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