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filingDate 2015-03-25-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_1c9d923ab508ce88c6b7dd0ed4ca8da9
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publicationDate 2015-12-02-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber GB-2526659-A
titleOfInvention Process for preparation of superparamagnetic hollow spherical nanostructures
abstract A process for preparation of superparamagnetic hollow spherical nanostructures characterised in that Fe2+/Fe3+ ions are absorbed onto the surface solid silicon dioxide (SiO2) cores pre-prepared by the Stober process, after which the silicon dioxide cores are dissolved using alkaline aqueous solutions of [2OH-/ HCO3-] ions and [CO32-/HCO3-] ions having pH value between 7 and 12, and that the Fe2+/Fe3+ ions in the form of superparamagnetic spinel iron oxide nanoparticles are precipitated with a precipitating reagent. The silicon dioxide cores may be suspended in distilled water so that their concentration is 0.25-2.0 mol% and this suspension in the volume percentage between 0.1 and 0.5 is added to an aqueous solution of Fe2+/Fe3+ ions with molar concentration of 0.2-0.15 mol/L and wherein the aqueous solutions of iron salts are based on nitrates, sulphates, chlorides and acetates.
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