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publicationDate 2013-02-20-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber GB-2493718-A
titleOfInvention Electrochemical sensor with surfactants
abstract An electrochemical method of measuring concentration of an analyte in a test fluid at a temperature of at least 50°C uses a sensor with a plurality of electrodes in contact with an electrolyte solution containing the analyte and a redox-active species electrochemically convertible between reduced and oxidised forms wherein the electrolyte solution contains surfactant and at least one said form of the redox active species is present within surfactant micelles. A voltammetric response is observed by applying varying potential to the electrodes and observing current flow as voltage is varied. The surfactant micelles enhance thermal stability of the redox active species and may also solubilise a species with poor water solubility, such as t-butylferrocene. The sensor may be incorporated in a downhole tool for measuring an analyte in a subterranean fluid.
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