http://rdf.ncbi.nlm.nih.gov/pubchem/patent/GB-2413554-A
Outgoing Links
Predicate | Object |
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assignee | http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_315ae544538aaeac6d1f4eed6754e4bb |
classificationCPCAdditional | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/Y02P20-55 |
classificationCPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07F1-02 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C08F36-04 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C08C19-44 |
classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07F1-02 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C08F36-04 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C08C19-44 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C08F4-48 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C08F4-46 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C08F12-08 |
filingDate | 2001-07-19-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
inventor | http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_c93f23a697920100080c83b44928141c http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_b190d02757d8341dc0193d5e627e525b |
publicationDate | 2005-11-02-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationNumber | GB-2413554-A |
titleOfInvention | Process of making protected aminofunctionalized polymerization initiators |
abstract | A process for making amine-functionalized compounds comprising reacting one or more omega-tertiary-amino-1-haloalkanes of formula (R<1>)(R<2>)N-Z-X wherein: Z is an optionally substituted straight or branched chain hydrocarbon group; R<1>, R<2> are protecting groups selected from alkyl, aralkyl, allyl, or R<1>, R<2> together form an optionally substituted benzopyrrolidine ring; X is halogen; with an alkali metal in an alkane, cycloalkane, or aromatic solvent or mixtures thereof, to form compounds of formula (R<1>)(R<2>)N-Z-M wherein M is an alkali metal. The compounds of formula (R<1>)(R<2>)N-Z-M may be chain extended by reacting with one or more unsaturated organic compounds to give a compound of formula (R<1>)(R<2>)N-Z-Qn-M wherein Q is a saturated or unsaturated hydrocarbyl group wherein: n is 0-5. The preferred alkali metal is lithium and the preferred halogen is chlorine. Preferably the process involves the preaparation of 3-[N,N-dibenzylamino]-1-propyllithium and 3-[(N-benzyl-N-methyl)amino]-1-propyllithium. |
priorityDate | 2000-09-19-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
type | http://data.epo.org/linked-data/def/patent/Publication |
Incoming Links
Total number of triples: 213.