http://rdf.ncbi.nlm.nih.gov/pubchem/patent/GB-2287030-A

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classificationCPCInventive http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C08G73-0266
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classificationIPCInventive http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C08J5-18
http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C08G73-02
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http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/H01B1-12
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filingDate 1995-02-24-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_a448e1a0e61766f9eb3c67bd13375879
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publicationDate 1995-09-06-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber GB-2287030-A
titleOfInvention Polyanilines and their manufacture
abstract A polyaniline is characterised by a nuclear magnetic resonance spectrum in its leuco form showing only two <13>C peaks, indicating the substantal absence of chain branching and preferably by a molecular weight (Mp) above 90,000 and up to about 170,000 (more especially 100 - 140,000). Oriented films of such polyanilines in the protonated emeraldine oxidation state have electrical conductivities up to at least around 6000S/cm. They may be made by oxidising aniline in aqueous solution with a persulphate under the combination of conditions that the acidity of the solution throughout the reaction is such that if its temperature is adjusted to 20 DEG C it will have a pH in the range from about -0.2 to +3.0; that the temperature of the solution is in the range from -5 to about -40 DEG C; that the solution contains at least sufficient inert ionic solute to maintain it in the liquid state; and that the persulphate is added to the solution always at a rate corresponding to a total addition time of at least six hours (but preferably not over 36 hours) and in a molar ratio to the aniline in the range from 1.1:1 to 1.4:1. <IMAGE>
isCitedBy http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-6936955-B1
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priorityDate 1994-03-04-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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Total number of triples: 23.