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classificationCPCInventive http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C08K5-0091
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filingDate 1991-09-16-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_b3b669e5e43ce801a820d1e772a39c21
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publicationDate 1993-03-17-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber GB-2259513-A
titleOfInvention Autoxidisable coating composition
abstract An autoxidisable coating composition (especially a paint, varnish or woodstain) comprises an autoxidisable film- forming polymer and a cobalt drier dispersed or dissolved in an organic or preferably aqueous volatile carrier liquid where the activity of the drier is promoted by the presence of a halogenated (preferably fluorinated) ( beta -keto ester either added as a complex with the cobalt or which forms such a complex in situ. The esterifying moiety of the beta -keto ester is aliphatic (including cycloaliphatic). The autoxidisable groups of the polymer may be derived from the condensation of allyl glycidyl ether or one of its analogues with a carboxylic acid moiety e.g. acrylic or methacrylic acids. The polymer preferably also comprises hydrophobic non-acid monomers e.g. alkyl acrylates, vinyl acetate and styrene. Alternatively the polymer may be an alkyd resin. The promoter is preferably (2,2,2-trifluoroethyl 3-oxobutanoate) or (ethyl,4,4,4-trifluoro-3-oxobutanoate). The invention also relates to a bis cobalt (II) ion complex, wherein the complexing moiety is a promoter as defined above, particularly, bis (ethyl 4,4,4-trifluoro-3-oxobutanato) cobalt (II). <IMAGE>
priorityDate 1991-09-16-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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