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filingDate 1980-06-16-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationDate 1981-01-28-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber GB-2052525-A
titleOfInvention Method for the preparation of shaped articles of vinyl chloride based resin with improved surface properties
abstract A method for preventing bleeding of a plasticizer or other additive ingredients on the surface of from a vinyl chloride-based resin article comprises blending the vinyl chloride resin prior to fabrication into shaped articles, with 0.5 to 50% by weight of a crosslinking aid selected from allyl group-containing compounds, e.g. triallyl cyanurate and triallyl isocyanurate, and esters of methacrylic acid, e.g. diethyleneglycol dimethacrylate and trimethylolpropane trimethacrylate and then fabricating into a shaped article, which is then exposed to low temperature plasma of a gas having no polymerizability in the plasma condition, e.g. carbon monoxide, so that a barrier layer with a controlled degree of crosslinking is formed in the surface. The effect is very durable over a long period of time so that plasticizer bleeding is effectively prevented even after prolonged outdoor use or weathering.
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