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filingDate 1909-04-07-04:00^^<http://www.w3.org/2001/XMLSchema#date>
grantDate 1909-12-09-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationDate 1909-12-09-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber GB-190908438-A
titleOfInvention Improvements in the Manufacture of Halogenated Compounds of Indigo and Indigoid Bodies.
abstract 8438. Dreyfus, C., Tompkins, H. K., and Clayton Aniline Co. April 7. Halogenindigo dyes; halogenthioindigo dyes.- Dyes of the indigo or thioindigo classes are halogenated by treatment with chlorine or bromine in presence of antimony chlor-or brom-acetylide. Suitable diluents such as carbon tetrachloride, acetylene tetrachloride, or carbon bisulphide may also be present. The process can be applied to indigo, tolylindigo, #-naphthylindigo, mono- and di-chlor- and brom-indigo, indirubin, thioindigo, and dyes containing nitrogen and sulphur rings. The production of tri- and tetra-chlor-indigo, tribromindigo, chlorbromindigo, and tetrabromthioindigo is described in examples. The Provisional Specification also describes the production of monochlorindigo. Antimony chlor- and brom-acetylides are obtained by passing acetylene into antimony penta-chloride and bromide ; the antimony pentachloride is preferably employed mixed with a proportion of trichloride, and may be obtained by treating the metal with chlorine, or by chlorinating the trichloride. The chlor- and brom-acetylides are decomposed by chlorine and bromine with reformation of the pentachloride and pentabromide.
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