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classificationCPCInventive http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07J1-0037
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filingDate 1977-04-22-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationDate 1978-10-18-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber GB-1529416-A
titleOfInvention Preparation of 7-keto-steroids from 7-unsubstituted steroids
abstract 1529416 Preparation of 7-keto-steroids UPJOHN CO 22 April 1977 [26 April 1976] 16748/77 Heading C2U Steroids of the formula (wherein R 1 is H, benzoyloxy or C 1-6 alkanoyloxy; R 3 is H, phenyl or C 1-5 alkyl; and either R 17 α is H and R 17 # is a stigmastene side chain or is a cholestane side chain which may be substituted in position-25 by a hydroxy, benzoyloxy or C 1-6 alkanoyloxy group or R 17 α is CH 3 and R 17 # is OH or OCOCH 3 ) are prepared by oxidizing corresponding steroids unsubstituted in the 7-position using as oxidizing agent a complex of CrO 3 and a pyrazole of the formula wherein R A and R B are each H, CH 3 or phenyl. Stigmasteryl benzoate is prepared from stigmasterol and benzoyl chloride.
priorityDate 1976-04-26-04:00^^<http://www.w3.org/2001/XMLSchema#date>
type http://data.epo.org/linked-data/def/patent/Publication

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