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filingDate 1975-10-10-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationDate 1978-09-20-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber GB-1525574-A
titleOfInvention Process for preparation of 1,4-benzohydroquinone derivatives
abstract 1525574 Preparation of 1,4-benzohydroquinone derivatives EISAI CO Ltd 10 Oct 1975 [11 Oct 1974] 41596/75 Heading C2C A process for the preparation of a 2,3- dimethoxy-5-substituted-6-methyl-1,4-benzohydroquinone or a 1-monoester thereof of formula wherein R 1 is H or an acyl group and R 2 represents wherein n is 0 or an integer from 1 to 11 and A and B each are hydrogen or they may form a valence bond to form a double bond between the two carbon atoms to which they are attached, comprises reacting a 2,3-dimethoxy-6- methyl-1,4-benzoquinone or a monoester thereof of formula wherein R 1 is as defined above, with prenol or a derivative thereof having the formula or isoprenol or a derivative thereof of formula wherein X is a hydroxy group, a C 1-6 alkoxy group, an acyloxy group or a halogen atom and R 2 is as defined above, in the presence of an acidic catalyst for condensation which is adsorbed on an adsorbent. The examples describe the preparative of 2,3-dimethoxy-5-methyl-6- nonaprenyl-1,4-benzoquinone, 2,3-dimethoxy-5- methyl-6-decaprenyl-1,4-benzoquinone, 2,3-dimethoxy-5-methyl-6 - undecaprenyl - 1,4-benzoquinone, 2,3-dimethoxy-5-methyl-6-dodecaprenyl-1,4-benzoquinone and 2,3-dimethoxy-5- methyl-6-phytyl-1,4-benzoquinone.
priorityDate 1974-10-11-04:00^^<http://www.w3.org/2001/XMLSchema#date>
type http://data.epo.org/linked-data/def/patent/Publication

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