http://rdf.ncbi.nlm.nih.gov/pubchem/patent/GB-1492242-A
Outgoing Links
| Predicate | Object |
|---|---|
| assignee | http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_e2c9efaea5dccdc8052bc4dd188eafd9 |
| classificationCPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C08G18-10 |
| classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C08G18-00 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C08G18-10 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C08G18-82 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C08G18-65 |
| filingDate | 1976-03-15-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| publicationDate | 1977-11-16-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| publicationNumber | GB-1492242-A |
| titleOfInvention | Method of producing polyurethane products |
| abstract | 1492242 Polyurethanes BRIDGESTONE TIRE KK 15 March 1976 [14 March 1975] 10320/76 Heading C3R A polyurethane product having improved flex crack resistance, cut resistance and tear strength is prepared by a method comprising curing (a) a polyurethane prepolymer having terminal NCO groups with (b) at least one curative selected from polyamines and polyols, and heat-treating the resultant product at a temperature of from 60-180‹ C. for from 1- 30,000 minutes in an atmosphere having an absolute humidity of at least 2% and generally up to 80%. The heat-treatment in humidified air may be carried out after the polyurethane product has been removed from the mould or after a post-cure heat-treatment in air. The prepolymer generally has a number average molecular weight of from 800 to 20,000 and may be a reaction product obtained by reacting a polyether, polyester or unsaturated hydrocarbon each having terminal active hydrogen atoms with a molar excess of an organic polyisocyanate. The preferred polyether is a polyoxyalkylene polyol, particularly polyoxytetramethylene glycol and the preferred polyester is a dihydroxy polyethylene adipate. The preferred unsaturated hydrocarbons are polybutadiene glycol, styrene-butadiene copolymer glycol, polyisoprene glycol or acrylonitrile-butadiene copolymer glycol. The preferred organic polyisocyanates are tolylene - 2,4 - or - 2,6 - diisocyanate, 1,5 - naphthalene diisocyanate, diphenyl - 4,4<SP>1 </SP>- diisocyanate, diphenylmethane- 4,4<SP>1</SP> - diisocyanate, hexane diisocyanate, cyclohexyl - 1,3 - or - 1,4 - diisocyanate, methylene bis(4 - cyclohexyl isocyanate), 1,3 - or 1,4 - xylene diisocyanate, 1 - methyl - cyclohexane- 2,4 - diisocyanate, decaline - 1,5 - diisocyanate, 3,31 - dimethyl biphenyl - 4,41 - diisocyanate or a mixture thereof. The preferred curatives are 4,41 - methylene bis(2 - chloroaniline), methylene dianiline, naphthalene - 1,5 - diamine, phenylene diamine, tolylene-2,4-diamine, diphenylether - 4,4<SP>1 </SP>- diamine, hydrazine, ethylene diamine, 2,6-dichlorophenylene diamine, hexamethylene - 1,6 - diamine, piperazine, ethylene glycol, 1,3-propylene glycol, 1,4-butane diol, trimethylolpropane, bis- (#,#<SP>1</SP> - hydroxyethoxy)naphthalene, bis(#,#<SP>1</SP>- hydroxyethoxy)benzene or a diamine of the formula where R is i-C 4 H 9 , R<SP>1</SP> is CH 3 or Cl and R<SP>11</SP> is a C 1 -C 4 alkyl radical. The equivalent ratio of the active hydrogen atoms in curative (b) to the NCO groups in prepolymer (a) generally ranges from 0À5 to 1À1. In the examples polyurethane elastomer sheets are prepared by heating either a polyoxytetramethylene glycol/ tolylene diisocyanate prepolymer or a polyethylene adipate/tolylene diisocyanate prepolymer with either 4,4<SP>1</SP>-methylene-bis(2-chloroaniline) or 1,4 - butane diol in a mould followed by the above heat-treatment in humidified air. |
| isCitedBy | http://rdf.ncbi.nlm.nih.gov/pubchem/patent/EP-3838940-A1 http://rdf.ncbi.nlm.nih.gov/pubchem/patent/WO-2021122295-A1 |
| priorityDate | 1975-03-14-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| type | http://data.epo.org/linked-data/def/patent/Publication |
Incoming Links
Total number of triples: 62.