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filingDate 1974-08-12-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationDate 1977-06-10-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber GB-1476163-A
titleOfInvention Organopolysiloxane compositions
abstract 1476163 Inhibited curable polysiloxane compositions GENERAL ELECTRIC CO 12 Aug 1974 [21 Nov 1973] 35372/74 Heading C3T An inhibited curable composition comprises (a) an unsaturated polysiloxane of average unit formula R a R<SP>1</SP> b SiO 4-a-b/2 , (b) a hydrogen polysiloxane of average unit formula R a H b SiO 4-a-b/2 wherein each R is a monovalent hydrocarbon, halohydrocarbon or cyanoalkyl radical, R<SP>1</SP> is an aliphatically unsaturated hydrocarbon radical, a is 0-3, b is 0À005-2 and a+b is 0À8-3, (c) sufficient Pt catalyst to cause reaction of (a) with (b), and (d) an inhibiting amount of an unsaturated isocyanurate wherein each R<SP>11</SP> is H or an alkyl, aryl, aralkyl, heteroaryl or C 1-6 alkenyl radical, at least one being a C 1-6 alkenyl radical. In Examples 1-7 Components A are prepared containing a vinyl-terminated polydimethylsiloxane gum or oil, the gum being mixed with a copolymer of Me 3 SiO 0À5 and SiO 2 units with 7 % MeViSiO units, ground quartz filler, a pigment or C black, a Pt catalyst and 0À05-1% of triallyl isocyanurate; Components B are prepared from the same gum or oil, mixed with a copolymer of and SiO 2 units or of Me 2 HSiO 0 . 5 , MeHSiO and Me 2 SiO units, and ground quartz; A and B are mixed in 10 : 1 to 1 : 1 ratio to give compositions stable at room temperature but curable at 100‹ C. In Example 9 diallyl, diallyl ethyl and dipropyl allyl isocyanurates are used. In Example 8 a simple mixture of (MeViSiO) 4 and (MeHSiO) 4 (I : 1 by weight) with H 2 PtCl 6 and triallyl isocyanurate is prepared.
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Total number of triples: 30.