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filingDate 1976-03-25-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationDate 1977-05-04-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber GB-1472245-A
titleOfInvention Production of polyurethane foam materials
abstract 1472245 Fire-reslstant, rigid, cellular isocyanurate polyurethanes GAF CORP 25 March 1976 [16 June 1975] 12096/76 Heading C3R Thermally stable, rigid, cellular isocyanurate polyurethanes are obtained by reacting polyols including an unhalogenated polyol and 2,3- dibromo-2-butenediol-1,4 with a polyalkylene polyphenyl polyisocyanate in proportions such that the hydroxy groups present in the total of the polyols are less than 50% of the number of isocyanato groups in the polyisocyanurate; together with a blowing agent; an isocyanate trimerization catalyst; antimony oxide and hydrated alumina. The total polyol used in the reaction mixture may contain, by weight, 50 to 70% brominated butenediol and 30 to 50% of an unhalogenated polyol such as a polyester, polyether or polycaprolactone having hydroxy numbers of 200 to 1000. The antimony oxide and hydrated alumina may be present in proportions by weight of the polyisocyanate of 1 to 20% and 10 to 100% respectively. In a typical example propoxylated sucrose, 2,3- dibromo - 2 - butenediol - 1,4 and polyphenylmethylene polyisocyanate mixed with trichlorofluoromethane; a catalyst comprising an amine polyol and 2,4,6-tris-(dimethylaminomethyl)phenol; antimony oxide, particle size 1 micron; alumina trihydrate, particle size 6À5 to 9À5 microns and a silicone block copolymer surfactant are poured into an open mould, allowed to foam and after 2 minutes the product placed in a curing oven at 90‹ C. for 1 hour to complete the formation of isocyanurate rings.
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