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filingDate 1974-05-31-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationDate 1977-04-21-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber GB-1471186-A
titleOfInvention Process for the preparation of a sulphone or of a mixture of sulphones
abstract 1471186 Sulphones KERNFORSCHUNGSANLAGE JULICH GmbH 31 May 1974 [2 June 1973] 24314/74 Heading C2C [Also in Divisions C3 and C7] Sulphones are prepared by electrolysing a solution of SO 2 to form SO 2 <SP>-</SP> ions which are reacted with organic compounds containing one or more atoms or groups replaceable by the SO 2 <SP>-</SP> ions, e.g. halogen compounds, sulphonic acid esters or sulphuric acid esters. Suitable solvents include acetonitrile or an excess of the organic reactant. A substance to promote conductivity may be added, e.g. a tetraalkylammonium salt. The organic reactant may be added before or after the formation of the SO 2 <SP>-</SP> ions. The reaction may be effected in a cell subdivided into an anode chamber and a cathode chamber by means of a diaphragm or an ion exchanger membrane. Examples prepare dibutylsulphone from n-butyl bromide and benzo[c]thiophen dioxide from o-xylylene dibromide. Other specified starting materials are dimethyl sulphate, chloroacetonitrile and chloracetone.
priorityDate 1973-06-02-04:00^^<http://www.w3.org/2001/XMLSchema#date>
type http://data.epo.org/linked-data/def/patent/Publication

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