http://rdf.ncbi.nlm.nih.gov/pubchem/patent/GB-1463460-A
Outgoing Links
| Predicate | Object |
|---|---|
| assignee | http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_c902faf6ae746c51fc8010672fc22894 |
| classificationCPCAdditional | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/Y10S521-902 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C08G2115-02 |
| classificationCPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C08G18-18 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C08G18-168 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C08G18-701 |
| classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C08G18-70 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C08G18-18 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C08G18-16 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C08G18-00 |
| filingDate | 1975-06-18-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| publicationDate | 1977-02-02-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| publicationNumber | GB-1463460-A |
| titleOfInvention | Polyurethanes |
| abstract | 1463460 Polyurethanes UPJOHN CO 18 June 1975 [24 June 1974] 26006/75 Heading C3R In a process for the reaction of a polyisocyanate with a polyol in the presence of a catalyst to obtain a polymer containing urethane linkages, the improvement comprises employing as the catalyst an aminimide corresponding to the formula wherein R 1 , R 2 and R 4 are monovalent hydrocarbyl radicals containing in the case of R 1 and R 2 from 1-12 carbon atoms, and in the case of R 4 from 1-17 carbon atoms, R 1 and R 2 taken together with the N atom to which they are attached additionally represent a heterocyclic radical, R 3 is a C 2 -C 12 hydroxyalkyl radical, a C 3 -C 12 hydroxyalkoxyalkyl radical or a C 1 -C 12 monovalent hydrocarbyl radical, and R 5 is a C 1 -C 12 divalent hydrocarbyl radical, the reaction being initiated at a temperature below the dissociation temperature of the aminimide. The reaction is generally initiated at ambient temperature and is carried out without the application of heat. The aminimides are generally employed in an amount of from 0À0005 moles up to 0À03 moles per equivalent of polyisocyanate and is preferably added to the reaction mixture as a solution in the polyol component or in a polyol having a M.Wt. of less than 600. The polyisocyanate and polyol may be reacted under foam-forming conditions to produce a polyurethane foam. The aminimide catalyst may be used in combination with an isocyanate - trimerization catalyst, e.g. an epoxide whereby a polyisocyanurate-polyurethane foam is obtained, and optionally additionally in the presence of a catalyst which promotes the formation of carbodiimide groups. Preferred aminimides are bis(trimethylamine)- sebacimide, dimethyl-(2-hydroxy-3-butoxypropyl)amine methacrylimide, dimethyl - (2- hydroxypropyl)amine laurimide and dimethyl - (2 - hydroxypropyl)amine myristimide. In Example 1 a rigid polyurethane foam is prepared from a polyol obtained by propoxylating a polymethylene polyphenyl polyamine mixture; propoxylated glycerol; an organosilicone surfactant; trichlorofluoromethane; bis(trimethylamine)sebacimide in polyethylene glycol (M.Wt. 400) and polymethylene polyphenyl polyisocyanate. In Example 2 a polyisocyanurate polyurethane foam is prepared from a polyester obtained by blending diethylene glycol with the product obtained by esterifying chlorendic anhydride with diethylene glycol and reacting the half ester with propylene oxide; an ethylene oxide/trimethylolpropane adducts an epoxy novolac resin; an organo-silicone surfactant; trichlorofluoromethane; polymethylene polyphenyl polyisocyanate; tris(2- chloroethyl)phosphate; bis(trimethylamine) - sebacimide in polyethylene glycol; and sodium N - (2 - hydroxy - 5 - nonylphenyl)methyl - N- methylglycinate in diethylene glycol. In Example 3 rigid polyurethane foams are prepared as in Example 1 using as the aminimide catalyst dimethyl - (2 - hydroxy - 3 - butoxypropyl)amine methacrylimide, dimethyl-(2-hydroxypropyl)amine myristimide or dimethyl-(2- hydroxypropyl)amine laurimide. |
| priorityDate | 1974-06-24-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| type | http://data.epo.org/linked-data/def/patent/Publication |
Incoming Links
Total number of triples: 51.