http://rdf.ncbi.nlm.nih.gov/pubchem/patent/GB-1428941-A
Outgoing Links
Predicate | Object |
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assignee | http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_670101b0e1b717a61558c95d26de20eb |
classificationCPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C08F20-12 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C08F2-06 |
classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C08F4-42 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C08F20-12 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C08F4-00 |
filingDate | 1974-05-06-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationDate | 1976-03-24-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationNumber | GB-1428941-A |
titleOfInvention | Method for preparation of polymethacrylates by the anionic po lymerization |
abstract | 1428941 Anionic polymerization of methacrylates CESKOSLOVENSKA AKADEMIE VED 6 May 1974 [7 May 1973] 19847/74 Heading C3P Esters of methacrylic acid are polymerized anionically using as initiator an alphalithiosubstituted carboxylic acid ester. The process is carried out in an aromatic hydrocarbon or aliphatic ether at - 70‹ to + 50‹ C. The initiator may be prepared in situ from a substituted lithium amide and the appropriate carboxylic ester or from an organolithium compound, secondary amine and an appropriate carboxylic ester. A lithium alkoxide may also be present in the polymerization. In typical examples, methyl- or n-octyl methacrylate are polymerized in toluene using ethyl-α-lithioisobutyrate or mixtures thereof with lithium t-butoxide or (-)-menthoxide, or in situ initiator mixtures of n - butyl lithium / diisopropylamine / ethylisobutyrate or di-t-butyl-α,α<SP>1</SP>,α<SP>1</SP>-trimethylglutarate /N-lithium diisopropylamide. |
priorityDate | 1973-05-07-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
type | http://data.epo.org/linked-data/def/patent/Publication |
Incoming Links
Total number of triples: 36.