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filingDate 1973-02-22-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationDate 1975-09-24-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber GB-1407124-A
titleOfInvention Preparation of rubberized fabric
abstract 1407124 Rubberized fabric BF GOODRICH CO 22 Feb 1973 [22 Feb 1972] 8673/73 Heading B2E A process for rubberizing fabric comprises dipping the fabric in an aqueous dispersion containing an adhesive latex of a diene polymer and a dispersion of an acrylic polymer having most of the links in the polymer chain of the configuration in which R is H, methyl, ethyl, Cl or CN, and in which X in a majority of the links is O-alkyl where the alkyl group has 1 to 4 carbon atoms, X in minority of groups is OH, drying the fabric and subsequently rubberizing the fabric. The diene polymer may be a natural rubber latex. or a diene polymer latex such as of cis 1, 4-polyisoprene, or a copolymer predominantly of a diene such as butadiene or isoprene with a minor proportion of a comonomer such as styrene, acrylonitrile, or acrylic ester. The preferred material is a copolymer of butadiene, styrene and vinyl pyrridine. The acrylic polymer may be predominantly made from an acrylic or substituted acrylic ester such as ethyl acrylate, or methyl ethacrylate or some other compound of which a number are listed and containing acrylic acid or a homologue such as methacrylic acid. Preferably an acrylic amide such as acrylamide or N-methylol acrylamide or homologues may also be present, preferably in a minor amount but sufficient to be at least equivalent to that of the acid and preferably rendering the polymer heat-settable. Preferably a water-dispersable heat-setting resin such as a resorcinol-formaldehyde resin, a urea-formaldehyde or melamine-formaldehyde resin, or an epoxy resin may be present. A paraffin wax, preferably a high-melting relatively non-volatile microcrystalline paraffin wax, may be present. The fabric may be made of natural fibres such as cotton, linen, silk or wool or of synthetic material such as rayon, nylon, polyester, and polyvinyl alcohol. Inorganic material such as glass or steel may also be used. Some fibre materials are preferably pre-treated, for example polyesters are preferably treated with a polyisocyanate, glass with resorcinol-formaldehyde latex and steel with cobalt naphthenate. In a preferred embodiment of the invention a fabric of parallel cords is dipped under tension in the first dispersion, dried under tension and subsequently rubberized.
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