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filingDate 1972-08-02-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationDate 1975-05-14-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber GB-1394134-A
titleOfInvention Complex nickel compounds
abstract 1394134 Nickel complexes containing phosphorus ligands; adiponitrile E I DU PONT DE NEMOURS & CO 2 Aug 1972 [2 Aug 1971] 36120/72 Headings C2P and C2C Novel N-bonded nitrile complexes of zerovalent nickel of formula Ni(PXYZ) 3 R<SP>1</SP>CN where X is OR, Y and Z are R or OR and R is optionally substituted C 1-18 alkyl or aryl, the radicals R of a given PXYZ ligand optionally being cojoined, and being the same or different, the radicals R being chosen so that the ligand PXYZ has a cone angle having an average value between 130 and 200 degrees, and where R<SP>1</SP>CN is an organo nitrile, may be prepared by reacting a complex Ni(PXYZ) 3 or another suitable complex with R<SP>1</SP>CN. R<SP>1</SP> is preferably alkyl cyanoalkyl, aryl, fluoroaryl or C 3-20 alkenyl wherein the double bond is separated from CN by at least one carbon atom. The complexes may be used as catalysts in a process for the hydrocyanation of olefinic compounds, e.g. the hydrogenation of 3-pentenonitrile or 4-pentenonitrile to adiponitrile.
priorityDate 1971-08-02-04:00^^<http://www.w3.org/2001/XMLSchema#date>
type http://data.epo.org/linked-data/def/patent/Publication

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Total number of triples: 36.