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filingDate 1973-08-31-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationDate 1975-01-22-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber GB-1381088-A
titleOfInvention Thionophosphoric phosphonic acid oxima derivatives a process for their preparation and their use as insecticides
abstract 1381088 Phosphorus-containing cyano ketonoxime derivatives BAYER AG 31 Aug 1973 [2 Sept 1972] 41086/73 Headings C2P -and C2C Novel compounds of the formula in which R is C 1 -C 4 alkyl and R<SP>1</SP> is C 1 -C 4 alkyl or C 1 -C 4 alkoxy are obtained by reacting (CH 3 ) 3 C-C(CN)=N.OH in the form of an alkali metal-, alkaline earth metal- or ammonium salt thereof or in the presence of an acid binding agent with an ester halide: (RO)(R<SP>1</SP>)P(S)Hal in which Hal is halogen. The reaction is preferably effected in an inert solvent or diluent. The products have pesticidal properties and are active against insects and ectoparasites. They may be used as active ingredients in conventional pesticidal formulations. 1 - Cyano - 1 - tertbutylketonoxime is prepared by reacting trimethylacetic acid anilide with thionyl chloride to give the imide-chloride, reacting the latter with copper cyanide to give the corresponding α-imino-nitrile derivative and converting the latter to the oxime.
priorityDate 1972-09-02-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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