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filingDate 1972-04-04-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationDate 1974-12-27-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber GB-1378519-A
titleOfInvention Method of bending
abstract 1378519 Adhesives; bonding reinforcing materials to rubber DUNLOP Ltd 4 April 1972 [17 April 1971] 9745/71 Headings C3E and C3P [Also in Division D1] Adhesive compositions comprise a latex of a copolymer of an unsaturated aminimide with a co-monomer which results in a rubbery copolymer. The adhesives may also contain a resin precursor. Suitable aminimides are those of formula in which X 1 , X 2 and X 3 are hydrogen or saturated or unsaturated organic groups and X is an unsaturated organic group, particularly a group derived from a mono- or di-carboxylic unsaturated acid. The co-monomer may be a lower alkene, a conjugated diene or an alkyl acrylate, and additional co-monomers may also be present. The resin precursor may comprise resinforming reactants or a partially condensed resin, e.g. an aldehyde resin or a low or medium M.W. polyepoxy resin. In examples, adhesives are formed from butadiene/styrene/aminimide or butadiene / styrene / aminimide latices and either a pre-condensed resorcinol/formaldehyde resin or a glycidyl ether/diol condensate. Various different aminimide monomers are used, typical being N-dimethyl-N-[2-hydroxy-3-oxy- (4<SP>1</SP>-tertiary butyl phenyl)] - propylamino methacrylimide and N-dimethyl-N-[2-acetoxyl- 3 - oxy - (4<SP>1</SP> - tertiary butyl phenyl)]propylamino (4<SP>11</SP>-vinyl) benzoylimide. The above-described adhesives are used to bond reinforcing materials to natural or synthetic rubber compositions. The reinforcing material, e.g. cords formed from polyester, rayon or unplated steel, is coated with the adhesive; the coating heated to a temperature above that at which the aminimide groups are pyrolized to give isocyanate groups; the coated material optionally dipped in a conventional RF latex dip; the coated material then assembled with the natural or synthetic rubber composition; and the assembly vulcanized.
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