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filingDate 1973-04-10-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationDate 1974-09-25-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber GB-1368227-A
titleOfInvention Halogenoalkanesulphonic acid amides their preparation and their use as acaricides
abstract 1368227 Halogenoalkansulphonic acid amides BAYER AG 10 April 1973 [11 April 1972] 17100/73 Heading C2C The novel sulphonic acid amides of Formula I wherein R and R<SP>1</SP> are independently H, halogen or a C 1 -C 6 alkyl group which may be substituted by halogen; Hal is halogen; R<SP>11</SP> is H, C 1 -C 6 alkyl or C 2 -C 4 alkenyl; Y is H or trichloromethyl and Ar is phenyl, naphthyl, benzyl or phenethyl any of which may be substituted by F, Cl, Br, NO 2 , CN, CF 3 , CCl 3 , C 1-4 alkyl, C 1-4 alkoxy, C 1-4 alkylthio or C 2-4 alkenyl, may be prepared (a), when Y in Formula I is hydrogen, by reacting a halogenoalkane sulphonic acid amide of Formula II with paraformaldehyde and thionylchloride or anhydrous hydrogen chloride to form a chloromethyl compound of Formula V which is then reacted with a mercaptan or thiophenol of formula the latter being reacted in the presence of an acid binding agent, or in the form of a salt thereof or (b) by heating a compound of Formula II with chloral or paraformaldehyde and a mercaptan or thiophenol in the presence of an acid catalyst and removing the stoichiometric amount of water. Chloromethanesulphonic acid N - methyl - N- chloromethylamide is prepared by reacting chloromethanesulphonic acid monomethylamide paraformaldehyde or thionyl chloride in dichloromethane. The compounds of Formula I have activity as acaricidal agents and can be formulated into compositions with other known ingredients.
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priorityDate 1972-04-11-04:00^^<http://www.w3.org/2001/XMLSchema#date>
type http://data.epo.org/linked-data/def/patent/Publication

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