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filingDate 1973-03-06-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationDate 1974-09-18-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber GB-1367044-A
titleOfInvention Thiol-or thionothiol-phosphoric or-phosphonic acid esters process for their preparation and their use as insecticides and acaricides
abstract 1367044 Pesticidal thiophosphorus esters; benzyl mercapto thioethers BAYER AG 6 March 1973 [7 March 1972] 10760/73 Headings C2P and C2C Novel compounds of Formula I where R 1 is optionally halogen-substituted C 1-6 alkyl or alkoxy, R 2 is optionally halogen-substituted C 1-6 alkyl, R 3 is C 1-6 alkyl, X is oxygen or sulphur, Y is chlorine and n is 0, 1 or 2 may be prepared by reacting a salt of Formula II where M is a metal equivalent or ammonium with a compound of Formula III where Hal is chlorine or bromine. The starting material, benzylmercaptomonochloromethyl ethyl thioether, may be prepared by reacting benzyl mercaptan with monochloromethyl ethyl thioether to give benzylmercaptomethyl ethyl thioether and chlorinating this product, e.g. with sulphuryl chloride or chlorine. The compounds of Formula I have insecticidal, acaricidal, fungitoxic and rodenticidal properties and may be used as the active ingredients in conventional pesticidal compositions.
priorityDate 1972-03-07-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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