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filingDate 1971-10-19-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationDate 1974-06-12-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber GB-1356560-A
titleOfInvention Terpene aryl ether
abstract 1356560 Terpene aryl ethers CIBA-GEIGY AG 19 Oct 1971 [20 Oct 1970 23 Aug 1971] 35460/73 Divided out of 1355575 Heading C2C The invention comprises compounds of the formula wherein R 1 and R 2 represent a CH 3 or C 2 H 5 group, and either (i) Z 1 and Z 2 together represent an additional bond or an oxygen bridge, while Z 3 and Z 4 together represent an additional bond, or they each represent H atoms, or (ii) Z 1 , Z 2 Z 3 and Z 4 all represent H atoms. They may be obtained by (1) reacting a halide of the formula wherein X is a halogen atom, with 4-propargyloxyphenol, in the presence of an acid-binding agent; (2) reacting a compound of the formula with a compound of the formula in the presence of an acid-binding agent; or (3) when Z 1 and Z 2 together represent an oxygen bridge, reacting the corresponding compound in which Z 1 and Z 2 together represent an additional bond with an epoxidizing agent in the presence of an inert solvent. Examples are given for the preparation of the compounds. They are useful as pesticides, particularly as insecticides for the protection of crops, stored goods and livestock. 4-Propargyloxyphenol is obtained by reacting propargyl chloride with hydroquinone in the presence of K 2 CO 3 , KI and acetone. 1 - (4 - Hydroxyphenoxy) - 3,7 - dimethyl- 2,6-octadiene is obtained by reacting 1-bromo- 3,7-dimethyl-2,6-octadiene with hydroquinone in 1,2-dimethoxyethane and KOH in ethanol.
priorityDate 1970-10-20-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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