http://rdf.ncbi.nlm.nih.gov/pubchem/patent/GB-1356331-A
Outgoing Links
Predicate | Object |
---|---|
assignee | http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_a3ae63500ac7f6553fdf267a475ed01c |
classificationCPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J23-28 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C51-252 |
classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/B01J23-28 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C51-25 |
filingDate | 1971-09-27-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationDate | 1974-06-12-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationNumber | GB-1356331-A |
titleOfInvention | Process for the preparation of acetic acid |
abstract | 1356331 Acetic acid STAMICARBON NV 27 Sept 1971 [6 Oct 1970 (2)] 44936/71 Heading C2C Acetic acid is prepared by oxidizing n-butene with an oxygen-containing gas in the presence of steam at above 200‹ C. and a pressure greater than 2 bars in the presence of a supported tin oxide-molybdenum oxide catalyst. The tin oxide is in the form of particles of not more than 50 Š average diameter and the gaseous reaction mixture contains an O 2 /n-butene ratio of from 1 : 1 to 12 : 1 and a steam/n-butane ratio of from 2 : 1 to 10 : 1, the conditions of supply and reaction being such that the gaseous reactants in the reaction space comprise more than 2% by volume of n-butene and less than 11% by volume of oxygen. A fixed bed or fluidized reactor may be used for a gaseous feed stream of more than 2% of n-butene and less than 11% of oxygen, but for a feed stream of more than 11% of oxygen and less than 2% butene, a second feed stream of n-butene is used. By-product maleic acid, methyl ethyl ketone, and acetaldehyde may be present and the ratio of tin oxide to molybdenum oxide may be from 4 : 1 to 1 : 4 and silica, alumina, titania, clay or pumice may be used as carriers. |
isCitedBy | http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-6429331-B1 http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-6692706-B2 |
priorityDate | 1970-10-06-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
type | http://data.epo.org/linked-data/def/patent/Publication |
Incoming Links
Total number of triples: 40.