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classificationCPCInventive http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J23-28
http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C51-252
classificationIPCInventive http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/B01J23-28
http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C51-25
filingDate 1971-09-27-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationDate 1974-06-12-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber GB-1356331-A
titleOfInvention Process for the preparation of acetic acid
abstract 1356331 Acetic acid STAMICARBON NV 27 Sept 1971 [6 Oct 1970 (2)] 44936/71 Heading C2C Acetic acid is prepared by oxidizing n-butene with an oxygen-containing gas in the presence of steam at above 200‹ C. and a pressure greater than 2 bars in the presence of a supported tin oxide-molybdenum oxide catalyst. The tin oxide is in the form of particles of not more than 50 Š average diameter and the gaseous reaction mixture contains an O 2 /n-butene ratio of from 1 : 1 to 12 : 1 and a steam/n-butane ratio of from 2 : 1 to 10 : 1, the conditions of supply and reaction being such that the gaseous reactants in the reaction space comprise more than 2% by volume of n-butene and less than 11% by volume of oxygen. A fixed bed or fluidized reactor may be used for a gaseous feed stream of more than 2% of n-butene and less than 11% of oxygen, but for a feed stream of more than 11% of oxygen and less than 2% butene, a second feed stream of n-butene is used. By-product maleic acid, methyl ethyl ketone, and acetaldehyde may be present and the ratio of tin oxide to molybdenum oxide may be from 4 : 1 to 1 : 4 and silica, alumina, titania, clay or pumice may be used as carriers.
isCitedBy http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-6429331-B1
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priorityDate 1970-10-06-04:00^^<http://www.w3.org/2001/XMLSchema#date>
type http://data.epo.org/linked-data/def/patent/Publication

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