http://rdf.ncbi.nlm.nih.gov/pubchem/patent/GB-1355405-A
Outgoing Links
| Predicate | Object |
|---|---|
| assignee | http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_2dbb2d7ecbd600cf89fbdd230f4a466c |
| classificationCPCAdditional | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/Y10T428-31623 |
| classificationCPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C08G73-12 |
| classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C08G73-12 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C08G73-10 |
| filingDate | 1972-02-24-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| publicationDate | 1974-06-05-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| publicationNumber | GB-1355405-A |
| titleOfInvention | Heatstable polyimide resins |
| abstract | 1355405 Laminates RHONE-POULENC SA 24 Feb 1972 [24 Feb 1971] 8655/72 Heading B5N [Also in Division C3] A heat-stable resin comprises recurring units where is a is 0 to 5 ; Y is H, CH 3 or Cl ; G is a monovalent aromatic radical; A is a C 2 or higher divalent organic radical; and the proportion of units wherein a is 0 is such that there are between 4À4 and 20 =D 1 = radicals per =N-N= radical. The resin may also contain units and/or molecules wherein T is a monovalent organic radical; T, is a radical or and b is 0 to 4. They may be prepared by heating at 50 to 350‹ C. one mol of an alazine G-CH=N-N=CH-G with 2À2 to 10 mols of a bis-imide and optionally up to 30 mol per cent related to the bis-imide of a mono-imide A prepolymer may first be formed in bulk or solution at up to 180‹ C. and cured by subsequent heating. In a further embodiment up to 50% (by weight of bis-imide + alazine) of an unsaturated polyester and/or a polymerizable vinyl, maleic, allyl or acrylic monomer containing a -CH=C= group may be heated with the reactants or the prepolymer. Numerous reactants are exemplified and curing may be effected in the presence of polymerization initiators such as lauroyl peroxide or azo-bisisobutyronitrile or diazabicyclooctane. Up to 10 wt. per cent of an aromatic compound containing 2 to 4 benzene rings and boiling above 250‹ C. may be added to the resin to lower the softening point of the prepolymer. The prepolymers may be used as a liquid mass, e.g. for hot casting; cooled and ground to powders, e.g. for compression moulding optionally with powdered, spherical, granular, fibrous or flake fillers; or as suspensions or solutions for coatings or forming pre-pregs by impregnating fibrous materials consisting of aluminium or zirconium silicate or oxide, carbon, graphite, boron, asbestos or glass. Specified uses of the resins are insulation for transformers and printed circuits, gears and self-lubricating bearings. In examples prepolymers are prepared from N,N<SP>1</SP>-4,4<SP>1</SP>-diphenyl methane orether or m-phenylene-bis-maleimide and benzalazene, and in Example 8 additionally N-phenyl maleimide. In Example 6 63 g. of prepolymer are further heated with 7 g. of (i) terphenyl, (ii) allyl phthalate or (iii) an unsaturated polyester of ethylene glycol and chlorendic and maleic acids. The products are cooled and ground and the resulting powder of less than 100 Á moulded alone or after mixture with diazabicyclooctane and 3 mm. glass fibres except in Example 5 where the powder is suspended in water and used to impregnate satin type glass fibre fabric which has been desized and then treated with γ-aminopropyltriethoxy silane. 12 layers of the impregnated and dried fabric are stacked with weft and warp alternating and laminated at 250‹ C. and 40 bars. Reference is made to Specifications 1,190,718, 1,238,043 and 1,355,406. |
| priorityDate | 1971-02-24-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| type | http://data.epo.org/linked-data/def/patent/Publication |
Incoming Links
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