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filingDate 1970-02-05-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationDate 1972-07-12-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber GB-1281653-A
titleOfInvention Micro granules containing pesticides and process for their manufacture
abstract 1281653 Microgranules containing pesticides FARBWERKE HOECHST AG 5 Feb 1970 [5 Feb 1969] 5528/70 Heading ASE Microgranules having a granular particle size of from 0.075 to 0.4 mm comprise a homogenous content of a solid pesticidal active ingredient having a particle size of from 0.001 to 0.01 mm together with an adhesive, and, optionally, together with an inert substance, a wetting agent, dispersing agent and protective colloid and being substantially free from water. The microgranules may be prepared by grinding a pesticide in the wet state together with an adhesive and optionally other substances, in a ball mill to yield a particle size of at most 0.01 mm, and spray-drying the suspension or paste thus obtained by means of discs rotating at a circumferential speed of from 80 to 100 m/sec. using single-feed nozzles under a spraying pressure of from 0.5 to 4 atmospheres gauge, at a drying gas inlet temperature of from 300‹ to 140‹C and at a drying gas outlet temperature of from 50‹ to 120‹C. The pesticide may have herbicidal, insecticidal, or fungicidal activity, e.g. pentachloronitrobenzene, linuron, monolinuron, diuron, endosulfan, or triphenyl tin acetate; the adhesive may be the sodium salt of lignin sulphonic acid, polyvinyl acetate, vinyl acetate copolymers, partially hydrolyzed polyvinyl alcohols, carboxymethyl cellulose, vegetable rubber or glue; the inert substance may be diatomaceous earth, silicic acid, kaolinite-containing quartz, alumina, chalk, bentonites, atta-clay, inorganic salts, milk powder or starch; and the dispersing and/or wetting agent may be the sodium or ammonium salt of lignin sulphonic acid, the sodium salt of dinaphthylmethane-disulphonic acid, butylnaphthalene sulphonic acid, oleylmethyl tauride and an alkyl phenylsulphonic acid or a condensation product of a fatty acid and albumin.
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