http://rdf.ncbi.nlm.nih.gov/pubchem/patent/GB-1268152-A

Outgoing Links

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filingDate 1970-06-08-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationDate 1972-03-22-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber GB-1268152-A
titleOfInvention Nitrosylation reaction
abstract 1,268,152. Discharge treatment apparatus. MONSANTO CO. 8 June, 1970 [6 June, 1969 (2)], No. 27551/70. Heading H5H. [Also in Division C2] An electric discharge apparatus comprises an inner electrode assembly 1 including a dielectric conduit 2 containing an electrically conductive fluid 3, an outer electrode assembly 7 including a dielectric conduit 8 connected in concentric relationship to conduit 2 by fittings 9 and 10 to form a discharge zone 11 between the conduits, the-outer electrode 7 also includes a metal electrode 12, a metal foil mounted on and wrapped around conduit 8 and current collectors 13 mounted thereon and connected to earth and the secondary of transformer 14 by wire 15, the inner electrode and conductive fluid 3 are connected by wire 16 to the high voltage secondary of the transformer 14, the apparatus also includes a gas inlet 17 and valve 18 and a heating jacket 19 for vaporizing the liquid organic reactant before its entry into discharge zone 11, an outlet conduit 20, and a heat exchanger jacket 21 mounted on conduit 8. In another embodiment, provision is made for continuously recycling liquid organic reactant. In a further embodiment, the inner electrode assembly 51 is constructed of stainless steel, fitted with a gasket 52 to an outer electrode assembly constructed of quartz tube 53 which itself is fitted with a variable length glass jacket 54, the rest of the apparatus of this embodiment is of similar construction to the previous embodiments. In another further embodiment, the discharge apparatus comprises a tubular chamber 71 having metal electrodes 72 and 73 connected to positive and negative terminals of a D.C. source, and an inlet 74 and outlet 75. In a final embodiment, the discharge apparatus is similar to that described in the first embodiment except that the, transformer is in a circuit suitable for delivering pulses of charge to the reactor, the circuit comprises a D.C. source 181 with its positive terminal connected to the anode of a silicon controlled rectifier 182, a resistor 183 connected across the anode and gate of rectifier 182 and to capacitor 184, a capacitor 185 connected across the primary of transformer 114 through ammeter 186 and silicon controlled rectifier 187, a pulse generator 188 connected to the gate of rectifier 187 and to the circuit between the cathode side of rectifier 187 and the negative pole of current source 181. In operation, rectifier 182 is normally biased open to charge capacitor 185, rectifier 187 is biased closed until it receives a pulse from generator 188, whereupon it opens and capacitor 185 discharges through the transformer, causing a pulse of current to the reactor, rectifier 187 closes when the voltage on capacitor 185 drops to zero, rectifier closes while rectifier 187 is conducting.
isCitedBy http://rdf.ncbi.nlm.nih.gov/pubchem/patent/WO-2019050702-A1
priorityDate 1969-06-06-04:00^^<http://www.w3.org/2001/XMLSchema#date>
type http://data.epo.org/linked-data/def/patent/Publication

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Total number of triples: 20.